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Acta Cryst. (2009). E65, m8  [ doi:10.1107/S1600536808039949 ]

Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-[kappa]2N,P}palladium(II) dichloromethane hemisolvate

H. Liu and D. Shen

Abstract: There are two independent PdII complex molecules in the asymmetric unit of the title compound, [PdCl2{Fe(C5H5)(C24H19NP)}]·0.5CH2Cl2. One ferrocenyl ring of one complex molecule is disordered over two sites with half-occupancy for each component. Both PdII cations adopt a distorted square-planar coordination geometry with a bidentate [2-(diphenylphosphino)phenyliminomethyl]ferrocene ligand and two chloride anions.

Online 3 December 2008


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