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Volume 65 
Part 2 
Page m155  
February 2009  

Received 24 December 2008
Accepted 25 December 2008
Online 8 January 2009

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Key indicators
Single-crystal X-ray study
T = 296 K
Mean [sigma](C-C) = 0.004 Å
R = 0.032
wR = 0.089
Data-to-parameter ratio = 14.1
Details
Open access

Dichloridobis(phenyl 2-pyridyl ketone oxime)nickel(II) acetone solvate

Jing-Zhou Yina* and Guang-Xiang Liub

aJiangsu Key Laboratory for Chemistry of Low-dimensional Materials, Department of Chemistry, Huaiyin Teachers College, Huai'an 223300, People's Republic of China, and bAnhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing 246003, People's Republic of China
Correspondence e-mail: liugx@live.com

The Ni atom in the title compound, [NiCl2(C12H10N2O)2]·C3H6O, adopts a distorted octahedral geometry, being ligated by four N atoms from two different phenyl 2-pyridyl ketone oxime ligands and two Cl atoms. In the crystal structure, intermolecular O-H...Cl hydrogen bonds link the molecules into a chain structure along [010]. There is a [pi]-[pi] contact between the pyridine rings [centroid-centroid distance = 3.824 (5) Å].

Related literature

For related structures, see: Korpi et al. (2005[Korpi, H., Polamo, M., Leskela, M. & Repo, T. (2005). Inorg. Chem. Commun. 8, 1181-1184.]); Pearse et al. (1989[Pearse, G. A., Raithby, P. R. & Lewis, J. (1989). Polyhedron, 8, 301-304.]); Afrati et al. (2005[Afrati, T., Dendrinou-Samara, C., Zaleski, C. M., Kampf, J. W., Pecoraro, V. L. & Kessissoglou, D. P. (2005). Inorg. Chem. Commun. 8, 1173-1176.]); Stamatatos et al. (2006[Stamatatos, T. C., Vlahopoulou, J. C., Sanakis, Y., Raptopoulou, C. P., Psycharis, V., Boudalis, A. K. & Perlepes, S. P. (2006). Inorg. Chem. Commun. 9, 814-818.]); Papatriantafyllopoulou et al. (2007[Papatriantafyllopoulou, C., Aromi, G., Tasiopoulos, A. J., Nastopoulos, V., Raptopoulou, C. P., Teat, S. J., Escuer, A. & Perlepes, S. P. (2007). Eur. J. Inorg. Chem. pp. 2761-2774.]).

[Scheme 1]

Experimental

Crystal data

  • [NiCl2(C12H10N2O)2]·C3H6O

  • Mr = 584.13

  • Triclinic, [P \overline 1]

  • a = 9.0367 (11) Å

  • b = 12.9142 (16) Å

  • c = 13.0664 (16) Å

  • [alpha] = 105.4390 (10)°

  • [beta] = 92.232 (2)°

  • [gamma] = 108.183 (2)°

  • V = 1384.0 (3) Å3

  • Z = 2

  • Mo K[alpha] radiation

  • [mu] = 0.93 mm-1

  • T = 296 (2) K

  • 0.22 × 0.18 × 0.16 mm
Data collection

  • Bruker SMART APEX CCD area-detector diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2000[Bruker (2000). SADABS, SAINT and SMART. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.822, Tmax = 0.866

  • 6839 measured reflections

  • 4761 independent reflections

  • 4002 reflections with I > 2[sigma](I)

  • Rint = 0.021
Refinement

  • R[F2 > 2[sigma](F2)] = 0.032

  • wR(F2) = 0.089

  • S = 1.05

  • 4761 reflections

  • 338 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.26 e Å-3

  • [Delta][rho]min = -0.39 e Å-3

Table 1
Selected geometric parameters (Å, °)

Ni1-N3 2.0344 (18)
Ni1-N1 2.0418 (18)
Ni1-N4 2.0879 (17)
Ni1-N2 2.1188 (17)
Ni1-Cl1 2.3944 (6)
Ni1-Cl2 2.4153 (7)

Table 2
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
O2-H2...Cl2 0.82 2.27 2.9582 (18) 142
O1-H1...Cl1i 0.82 2.91 3.4612 (16) 127
O1-H1...Cl1 0.82 2.37 3.0542 (16) 141
Symmetry code: (i) -x+1, -y, -z+1.

Data collection: SMART (Bruker, 2000[Bruker (2000). SADABS, SAINT and SMART. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2000[Bruker (2000). SADABS, SAINT and SMART. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: AT2700 ).

Acknowledgements

This work was supported by the National Natural Science Foundation of China (grant No. 20731004), the Natural Science Foundation for Outstanding Scholars of Anhui Province, China (grant No. 044-J-04011) and the Natural Science Foundation of the Education Commission of Anhui Province, China (grant Nos. KJ2007B092 and KJ2008B004).

References

Afrati, T., Dendrinou-Samara, C., Zaleski, C. M., Kampf, J. W., Pecoraro, V. L. & Kessissoglou, D. P. (2005). Inorg. Chem. Commun. 8, 1173-1176.  [ISI] [CSD] [CrossRef] [ChemPort]
Bruker (2000). SADABS, SAINT and SMART. Bruker AXS Inc., Madison, Wisconsin, USA.
Korpi, H., Polamo, M., Leskela, M. & Repo, T. (2005). Inorg. Chem. Commun. 8, 1181-1184.  [ISI] [CSD] [CrossRef] [ChemPort]
Papatriantafyllopoulou, C., Aromi, G., Tasiopoulos, A. J., Nastopoulos, V., Raptopoulou, C. P., Teat, S. J., Escuer, A. & Perlepes, S. P. (2007). Eur. J. Inorg. Chem. pp. 2761-2774.  [ISI] [CSD] [CrossRef]
Pearse, G. A., Raithby, P. R. & Lewis, J. (1989). Polyhedron, 8, 301-304.  [CrossRef] [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Stamatatos, T. C., Vlahopoulou, J. C., Sanakis, Y., Raptopoulou, C. P., Psycharis, V., Boudalis, A. K. & Perlepes, S. P. (2006). Inorg. Chem. Commun. 9, 814-818.  [ISI] [CSD] [CrossRef] [ChemPort]

Acta Cryst (2009). E65, m155  [ doi:10.1107/S1600536808043961 ]

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