Acta Cryst. (2009). E65, m223  [ doi:10.1107/S1600536809001184 ]

Poly[bis(-hemihydrogen 2-phenylquinoline-4-carboxylato-²N,O)silver(I)]

X. Zhang, P. Wei and B. Li

Abstract: In the title compound, [Ag(C₁₆H_10.5NO₂)₂], the Ag^I cation (site symmetry 2) is coordinated by two N atoms in a near-linear AgN₂ arrangement. Two carboxylate O atoms from two additional 2-phenylquinoline-4-carboxylate ligands form long Ag-O bonds [2.6585 (17) Å], resulting in a distorted square-planar arrangement. The bridging ligands result in infinite corrugated sheets propagating in (010). An O-HO hydrogen bond, disordered about a twofold axis, completes the structure.

Online 23 January 2009

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