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Acta Cryst. (2009). E65, m223    [ doi:10.1107/S1600536809001184 ]

Poly[bis([mu]-hemihydrogen 2-phenylquinoline-4-carboxylato-[kappa]2N,O)silver(I)]

X. Zhang, P. Wei and B. Li

Abstract top

In the title compound, [Ag(C16H10.5NO2)2], the AgI cation (site symmetry 2) is coordinated by two N atoms in a near-linear AgN2 arrangement. Two carboxylate O atoms from two additional 2-phenylquinoline-4-carboxylate ligands form long Ag-O bonds [2.6585 (17) Å], resulting in a distorted square-planar arrangement. The bridging ligands result in infinite corrugated sheets propagating in (010). An O-H...O hydrogen bond, disordered about a twofold axis, completes the structure.

Related literature top

For the related coordination polymers containing MnII, CoII and CuII, see: Xiao et al. (2005); Xie et al. (2005) and Xie et al. (2006), respectively.

Experimental top

A mixture of silver nitrate (0.5 mmol) and 2-phenyl-4-quinolinecarboxylic acid (0.5 mmol) in H2O (8 ml) and ethanol (8 ml) was sealed in a 25 ml Teflon-lined stainless steel autoclave and kept at 413 K for three days. Orange prisms of (I) were obtained after cooling to room temperature with a yield of 27%. Anal. Calc. for C32H21AgN2O4: C 63.43, H 3.47, N 4.63%; Found: C 63.41, H 3.32, N 4.59%.

Refinement top

The H atoms were placed in calculated positions (C—H = 0.93 Å, O—H = 0.82Å) and refined as riding with and Uiso(H) = 1.2Ueq(carruer).

Computing details top

Data collection: SMART (Bruker, 2001); cell refinement: SAINT (Bruker, 2001); data reduction: SAINT (Bruker, 2001); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. A view of the structure of (I), expanded to show the Ag—N bonds, showing 30% probability displacement ellipsoids. Symmetry code: I: 1–x, y, –z–1/2.
[Figure 2] Fig. 2. Part of a polymeric sheet in (I).
Poly[bis(µ-hemihydrogen 2-phenylquinoline-4-carboxylato-κ2N,O)silver(I)] top
Crystal data top
[Ag(C16H10.5NO2)2]F(000) = 1224
Mr = 605.38Dx = 1.655 Mg m−3
Monoclinic, C2/cMo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2ycCell parameters from 3290 reflections
a = 7.2163 (6) Åθ = 2.3–27.5°
b = 20.5060 (17) ŵ = 0.87 mm−1
c = 16.5632 (12) ÅT = 293 K
β = 97.585 (3)°Prism, orange
V = 2429.5 (3) Å30.20 × 0.15 × 0.15 mm
Z = 4
Data collection top
Bruker SMART CCD
diffractometer		2791 independent reflections
Radiation source: fine-focus sealed tube2550 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.020
ω scansθmax = 27.5°, θmin = 2.3°
Absorption correction: multi-scan
(SADABS; Bruker, 2001)		h = −9→9
Tmin = 0.877, Tmax = 1.00k = −25→26
9257 measured reflectionsl = −21→20
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.029Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.067H-atom parameters constrained
S = 1.10 w = 1/[σ2(Fo2) + (0.0323P)2 + 1.551P]
where P = (Fo2 + 2Fc2)/3
2791 reflections(Δ/σ)max < 0.001
177 parametersΔρmax = 0.66 e Å−3
0 restraintsΔρmin = −0.33 e Å−3
Crystal data top
[Ag(C16H10.5NO2)2]V = 2429.5 (3) Å3
Mr = 605.38Z = 4
Monoclinic, C2/cMo Kα radiation
a = 7.2163 (6) ŵ = 0.87 mm−1
b = 20.5060 (17) ÅT = 293 K
c = 16.5632 (12) Å0.20 × 0.15 × 0.15 mm
β = 97.585 (3)°
Data collection top
Bruker SMART CCD
diffractometer		2791 independent reflections
Absorption correction: multi-scan
(SADABS; Bruker, 2001)		2550 reflections with I > 2σ(I)
Tmin = 0.877, Tmax = 1.00Rint = 0.020
9257 measured reflectionsθmax = 27.5°
Refinement top
R[F2 > 2σ(F2)] = 0.029H-atom parameters constrained
wR(F2) = 0.067Δρmax = 0.66 e Å−3
S = 1.10Δρmin = −0.33 e Å−3
2791 reflectionsAbsolute structure: ?
177 parametersFlack parameter: ?
0 restraintsRogers parameter: ?
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ag10.50000.224313 (10)−0.25000.03976 (9)
N10.4524 (2)0.22681 (7)−0.11903 (9)0.0305 (3)
O10.4807 (3)0.16931 (8)0.17478 (8)0.0506 (4)
H1O0.47500.17500.22340.061*0.50
O20.6459 (3)0.26118 (9)0.18437 (10)0.0555 (4)
C10.4841 (3)0.28414 (9)−0.07613 (11)0.0323 (4)
C20.4827 (4)0.34294 (10)−0.12074 (13)0.0468 (5)
H2A0.46190.3417−0.17730.056*
C30.5113 (4)0.40127 (11)−0.08202 (16)0.0562 (7)
H3A0.50940.4396−0.11210.067*
C40.5437 (4)0.40349 (11)0.00334 (16)0.0546 (6)
H4A0.56270.44360.02940.065*
C50.5477 (3)0.34808 (11)0.04857 (13)0.0446 (5)
H5A0.57120.35060.10510.054*
C60.5165 (3)0.28627 (9)0.01036 (11)0.0317 (4)
C70.5077 (3)0.22584 (9)0.05293 (11)0.0313 (4)
C80.4621 (3)0.17105 (10)0.00812 (11)0.0344 (4)
H8A0.44670.13190.03480.041*
C90.4376 (3)0.17227 (9)−0.07805 (10)0.0302 (4)
C100.3928 (3)0.11103 (9)−0.12467 (11)0.0331 (4)
C110.2740 (3)0.11181 (10)−0.19829 (12)0.0379 (4)
H11A0.22190.1510−0.21850.045*
C120.2330 (3)0.05444 (12)−0.24147 (13)0.0476 (5)
H12A0.15580.0555−0.29110.057*
C130.3063 (4)−0.00390 (12)−0.21119 (15)0.0570 (7)
H13A0.2773−0.0424−0.23990.068*
C140.4230 (4)−0.00520 (11)−0.13802 (15)0.0593 (7)
H14A0.4731−0.0446−0.11770.071*
C150.4659 (4)0.05159 (11)−0.09489 (12)0.0463 (5)
H15A0.54420.0502−0.04560.056*
C160.5497 (3)0.22006 (10)0.14510 (11)0.0356 (4)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.05874 (17)0.04506 (14)0.01656 (11)0.0000.00894 (9)0.000
N10.0388 (9)0.0352 (8)0.0176 (7)0.0017 (7)0.0040 (6)0.0002 (6)
O10.0877 (12)0.0478 (8)0.0152 (6)−0.0092 (8)0.0029 (7)−0.0008 (6)
O20.0607 (11)0.0753 (11)0.0275 (8)−0.0222 (9)−0.0048 (7)−0.0068 (7)
C10.0384 (10)0.0364 (10)0.0232 (9)0.0005 (8)0.0081 (8)−0.0004 (7)
C20.0718 (16)0.0412 (11)0.0289 (10)0.0025 (11)0.0122 (10)0.0043 (8)
C30.085 (2)0.0358 (11)0.0494 (14)−0.0001 (11)0.0162 (13)0.0038 (10)
C40.0766 (18)0.0373 (11)0.0498 (14)−0.0021 (11)0.0084 (12)−0.0110 (10)
C50.0549 (14)0.0462 (12)0.0330 (11)0.0004 (10)0.0066 (10)−0.0110 (9)
C60.0331 (10)0.0391 (10)0.0236 (9)0.0001 (8)0.0060 (7)−0.0047 (7)
C70.0313 (10)0.0447 (10)0.0179 (8)0.0001 (8)0.0036 (7)−0.0016 (7)
C80.0485 (12)0.0369 (9)0.0179 (8)−0.0024 (9)0.0046 (8)0.0019 (7)
C90.0364 (10)0.0368 (9)0.0176 (8)0.0005 (8)0.0039 (7)0.0010 (7)
C100.0457 (12)0.0347 (9)0.0194 (8)−0.0039 (8)0.0066 (8)0.0005 (7)
C110.0447 (12)0.0434 (11)0.0252 (9)−0.0031 (9)0.0035 (8)0.0000 (8)
C120.0557 (14)0.0549 (13)0.0309 (10)−0.0146 (11)0.0007 (10)−0.0074 (9)
C130.088 (2)0.0440 (12)0.0401 (12)−0.0171 (12)0.0113 (12)−0.0106 (10)
C140.101 (2)0.0359 (11)0.0414 (13)0.0018 (12)0.0110 (13)0.0044 (9)
C150.0723 (16)0.0412 (11)0.0243 (10)0.0009 (10)0.0023 (10)0.0027 (8)
C160.0385 (11)0.0488 (11)0.0193 (8)0.0033 (9)0.0031 (8)−0.0040 (8)
Geometric parameters (Å, º) top
Ag1—N12.2413 (15)C5—H5A0.9300
Ag1—N1i2.2413 (15)C6—C71.431 (3)
Ag1—O2ii2.6585 (17)C7—C81.363 (3)
Ag1—O2iii2.6585 (17)C7—C161.521 (2)
N1—C91.320 (2)C8—C91.415 (2)
N1—C11.377 (2)C8—H8A0.9300
O1—C161.280 (2)C9—C101.487 (3)
O1—H1O0.8200C10—C151.392 (3)
O2—C161.223 (3)C10—C111.395 (3)
O2—Ag1iii2.6585 (17)C11—C121.388 (3)
C1—C21.414 (3)C11—H11A0.9300
C1—C61.421 (3)C12—C131.376 (4)
C2—C31.360 (3)C12—H12A0.9300
C2—H2A0.9300C13—C141.382 (4)
C3—C41.403 (4)C13—H13A0.9300
C3—H3A0.9300C14—C151.380 (3)
C4—C51.359 (3)C14—H14A0.9300
C4—H4A0.9300C15—H15A0.9300
C5—C61.421 (3)
N1—Ag1—N1i177.38 (8)C8—C7—C16118.96 (17)
N1—Ag1—O2ii97.54 (6)C6—C7—C16123.08 (16)
N1i—Ag1—O2ii82.16 (6)C7—C8—C9121.59 (18)
N1—Ag1—O2iii82.16 (6)C7—C8—H8A119.2
N1i—Ag1—O2iii97.54 (6)C9—C8—H8A119.2
O2ii—Ag1—O2iii167.15 (8)N1—C9—C8121.72 (17)
C9—N1—C1118.51 (16)N1—C9—C10118.39 (15)
C9—N1—Ag1120.76 (12)C8—C9—C10119.90 (16)
C1—N1—Ag1118.86 (11)C15—C10—C11118.69 (18)
C16—O1—H1O109.5C15—C10—C9120.59 (18)
C16—O2—Ag1iii137.88 (16)C11—C10—C9120.70 (17)
N1—C1—C2117.98 (17)C12—C11—C10120.3 (2)
N1—C1—C6122.71 (17)C12—C11—H11A119.8
C2—C1—C6119.30 (17)C10—C11—H11A119.8
C3—C2—C1120.9 (2)C13—C12—C11120.3 (2)
C3—C2—H2A119.6C13—C12—H12A119.9
C1—C2—H2A119.6C11—C12—H12A119.9
C2—C3—C4119.9 (2)C12—C13—C14119.8 (2)
C2—C3—H3A120.0C12—C13—H13A120.1
C4—C3—H3A120.0C14—C13—H13A120.1
C5—C4—C3121.1 (2)C15—C14—C13120.5 (2)
C5—C4—H4A119.4C15—C14—H14A119.8
C3—C4—H4A119.4C13—C14—H14A119.8
C4—C5—C6120.6 (2)C14—C15—C10120.5 (2)
C4—C5—H5A119.7C14—C15—H15A119.8
C6—C5—H5A119.7C10—C15—H15A119.8
C5—C6—C1118.14 (18)O2—C16—O1125.35 (19)
C5—C6—C7124.57 (18)O2—C16—C7120.26 (18)
C1—C6—C7117.24 (16)O1—C16—C7114.37 (17)
C8—C7—C6117.95 (17)
Symmetry codes: (i) −x+1, y, −z−1/2; (ii) x−1/2, −y+1/2, z−1/2; (iii) −x+3/2, −y+1/2, −z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O1—H1O···O1iv0.821.682.470 (3)162
Symmetry code: (iv) −x+1, y, −z+1/2.
Selected geometric parameters (Å, º) top
Ag1—N12.2413 (15)
N1—Ag1—N1i177.38 (8)
Symmetry code: (i) −x+1, y, −z−1/2.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O1—H1O···O1ii0.821.682.470 (3)162
Symmetry code: (ii) −x+1, y, −z+1/2.
references
References top

Bruker (2001). SMART, and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.

Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122.

Xiao, H. P., Li, X.-H. & Cheng, Y.-Q. (2005). Acta Cryst. E61, m158.

Xie, G., Zeng, M.-H., Chen, S.-P. & Gao, S.-L. (20065). Acta Cryst. E61, m2273.

Xie, G., Zeng, M.-H., Chen, S.-P. & Gao, S.-L. (2006). Acta Cryst. E62, m397–m399.