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Acta Cryst. (2009). E65, m134  [ doi:10.1107/S1600536808043596 ]

Poly[(3-nitrobenzoato)([mu]3-1,2,4-triazolato)cobalt(II)]

X.-L. Qi

Abstract: In the title compound, [Co(C2H2N3)(C7H4NO4)]n, the CoII atom is five-coordinated by three triazolate ligands and one bidentate 3-nitrobenzoate anion in a distorted trigonal-bipyramidal geometry. The triazolate ligand bridges the CoII atoms, generating a two-dimensional net parallel to the ab plane, in which both the CoII atom and the triazolate ligand act as three-connected nodes. Two weak intermolecular C-H...O hydrogen bonds connect the nets.

Online 8 January 2009


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