Acta Cryst. (2009). E65, m181  [ doi:10.1107/S1600536809000786 ]

Diazidobis[4,4,5,5-tetramethyl-2-(1,3-thiazol-2-yl)-2-imidazoline-1-oxyl-3-oxide-²O,N]manganese(II)

J. L. Chang, Z. Y. Gao and K. Jiang

Abstract: In the crystal structure of the title compound, [Mn(N₃)₂(C₁₀H₁₄N₃O₂S)₂], the Mn(II) atom exhibits a roughly octahedral coordination geometry. The Mn(II) atom lies on an inversion centre, thus the asymmetric unit comprises one half-molecule. The metal center is six-coordinated by two azide anions and by two chelating 4,4,5,5-tetramethyl-2-(1,3-thiazol-2-yl)-2-imidazoline-1-oxyl-3-oxide nitronyl nitroxide radical ligands, leading to two six-membered chelate rings.

Online 14 January 2009

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