Acta Cryst. (2009). E65, m226  [ doi:10.1107/S1600536809002293 ]

{(+)-(1R,2R)-1,2-Diphenyl-2,2'-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrate

L.-W. Zhou

Abstract: In title complex, [Co(C₂₈H₂₂N₂O₂)(C₅H₅N)₂]ClO₄·1.5H₂O, the Co^III ion is in a slightly distorted octahedral coordination environment with the pyridine ligands in a trans arrangement. In addition to the cation and anion, the asymmetric unit also contains three half-occupancy solvent water molecules and all components are connected via intermolecular O-HO hydrogen bonds.

Online 23 January 2009

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