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Acta Cryst. (2009). E65, o246-o247  [ doi:10.1107/S1600536809000038 ]

2-Methoxybenzaldehyde 2,4-dinitrophenylhydrazone

H.-K. Fun, R. Kia and H. Kargar

Abstract: In the title compound, C14H12N4O5, an intramolecular N-H...O hydrogen bond generates an S(6) ring motif. The dihedral angle between the two benzene rings is 3.91 (3)°, which shows the molecule is almost planar. The para-nitro group is twisted from the benzene ring to which it is attached, making a dihedral angle of 8.50 (9)°. In the crystal structure, molecules are linked together by intermolecular C-H...O and intermolecular three-centred O...O [2.8646 (12)-2.9213 (11) Å] and O...N [3.0518 (11) Å] interactions. The crystal structure is further stabilized by intermolecular [pi]-[pi] interactions [centroid-to-centroid distances 3.5708 (6)-3.9728 (12) Å].

Online 8 January 2009


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