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Acta Cryst. (2009). E65, m170  [ doi:10.1107/S1600536809000439 ]

fac-Aquadichloridotris(tetramethylene sulfoxide-[kappa]S)ruthenium(II)

R. S. Srivastava, C. F. Gonzales and F. R. Fronczek

Abstract: The title molecule, [RuCl2(C4H8OS)3(H2O)], is the isomer with the two chloride ligands cis and the three S-coordinated tetramethylene sulfoxide ligands facial relative to the Ru(II) center. The Ru-Cl distances are 2.4161 (7) and 2.4317 (7) Å, the Ru-O distance is 2.1540 (19) Å, and the Ru-S distances are in the range 2.2254 (8)-2.2657 (7) Å, with the shortest being that trans to the aqua ligand. The coordinated water molecule forms intermolecular hydrogen bonds with Cl and sulfoxide O atoms.

Online 10 January 2009


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