Acta Cryst. (2009). E65, m156  [ doi:10.1107/S1600536808044280 ]

[1,2-Bis(diphenylphosphino)ethane-²P,P'](2-carboxylatothiophenolato-²O,S)nickel(II) methanol solvate

J. Miao, F. Li, H. Chen, D. Wang and Y. Nie

Abstract: In the title complex, [Ni(C₇H₄O₂S)(C₂₆H₂₄P₂)]·CH₃OH, the nickel(II) centre adopts an approximately square-planar geometry, with the Ni atom coordinating to the S and O atoms of the bidentate thiosalicylate ligand and the two P atoms of the chelating Ph₂PCH₂CH₂PPh₂ ligand. There is hydrogen bonding between the methanol solvent molecule and the carbonyl O atom of the thiosalicylate ligand.

Online 8 January 2009

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