Acta Cryst. (2009). E65, m243-m244  [ doi:10.1107/S160053680900350X ]

Dichlorido[1-(2-methylbenzyl)-3-(⁶-2,4,6-trimethylbenzyl)-1H-2,3-dihydrobenzimidazol-2-ylidene]ruthenium(II) dichloromethane solvate

H. Arslan, D. VanDerveer, S. Yasar, I. Özdemir and B. Çetinkaya

Online 4 February 2009

Key indicators

• Single-crystal X-ray study
• T = 153 K
• Mean (C-C) = 0.006 Å
• R factor = 0.049
• wR factor = 0.115
• Data-to-parameter ratio = 15.1

checkCIF/PLATON results

No syntax errors found




Alert level B
PLAT083_ALERT_2_B SHELXL Second Parameter in WGHT unusually Large.      38.00      

Alert level C
            Value of measurement temperature given =   153.000
            Value of melting point given =     0.000
PLAT029_ALERT_3_C _diffrn_measured_fraction_theta_full Low .......       0.98      
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for        C26     
PLAT380_ALERT_4_C Check Incorrectly? Oriented X(sp2)-Methyl Moiety        C16     
PLAT380_ALERT_4_C Check Incorrectly? Oriented X(sp2)-Methyl Moiety        C17     
PLAT380_ALERT_4_C Check Incorrectly? Oriented X(sp2)-Methyl Moiety        C15     
PLAT380_ALERT_4_C Check Incorrectly? Oriented X(sp2)-Methyl Moiety        C25     

Alert level G
PLAT333_ALERT_2_G Check Large Av C6-Ring C-C Dist. C9     -C14           1.42 Ang. 

   0 ALERT level A = In general: serious problem
   1 ALERT level B = Potentially serious problem
   6 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   2 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   5 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

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