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Acta Cryst. (2009). E65, m271  [ doi:10.1107/S1600536809004383 ]

Bis(5-chloroquinolin-8-olato-[kappa]2N,O)bis(propan-2-olato-[kappa]O)titanium(IV)

Y. Fazaeli, E. Najafi, M. M. Amini and S. W. Ng

Abstract: The TiIV atom in the title compound, [Ti(C9H5ClNO)2(C3H7O)2], is chelated by the substituted quinolin-8-olate anions in a distorted octahedral geometry. The N-donor atoms are in a cis alignment as are the O atoms of the propan-2-olate groups; the O atoms of the quinolin-8-olate groups are trans to each other. One C atom of one propan-2-olate group is disordered over two positions with occupancies of 0.733 (8):0.267 (8).

Online 13 February 2009


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