Acta Cryst. (2009). E65, m265-m266  [ doi:10.1107/S1600536809004176 ]

Bis(1,3-benzothiazol-2-amine-N³)silver(I) nitrate acetone solvate

C. E. Strasser, L.-A. de Jongh, S. Cronje and H. G. Raubenheimer

Abstract: In the title compound, [Ag(C₇H₆N₂S)₂]NO₃·C₃H₆O, the Ag^I ion is coordinated to two benzothiazol-2-amine ligands via the thiazole N atoms in an approximately linear arrangement. The dihedral angle between the mean planes of the two 1,3-benzothiazole groups is 5.9 (3)°. Both amine groups on the ligands are oriented in the same direction and are engaged in N-HO hydrogen bonding with the nitrate counter-anion, forming one-dimensional columns along the b-axis direction. Voids created by inefficient crystal packing are occupied by acetone solvent molecules which are disordered over two sites with occupancies of 0.563 (11) and 0.437 (11).

Online 11 February 2009

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