Acta Cryst. (2009). E65, m272  [ doi:10.1107/S1600536809004620 ]

Nitratotris(triphenylphosphine)copper(I) methanol solvate

G. Steyl

Abstract: The title compound, [Cu(NO₃)(C₁₈H₁₅P)₃]·CH₃OH, is a methanol solvate derivative of nitratotris(triphenylphosphine)copper(I). The complex crystallizes with three triphenylphosphine ligands coordinated to the copper centre, with an O-HO hydrogen bond observed between the nitrate ligand and the methanol solvent molecule. The coordination around the Cu^I centre is distorted tetrahedral.

Online 13 February 2009

Copyright © International Union of Crystallography
IUCr Webmaster