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Acta Cryst. (2009). E65, o477  [ doi:10.1107/S1600536809003869 ]

(E)-4-[(4-Methoxyphenyl)iminomethyl]-N,N-dimethylaniline

L. Sundararaman, H. Ramu, R. Kandaswamy and H. Stoeckli-Evans

Abstract: The title compound, C16H18N2O, an N-benzylideneaniline derivative with substituents on both aromatic rings, crystallizes with two independent molecules (A and B) in the asymmetric unit. Both molecules exist in the E configuration. The dihedral angle between the two aromatic rings is 8.20 (5)° for molecule A and 12.52 (6)° for molecule B, and the imino C-N torsion angle ([tau]) is 7.1 (2)° for molecule A and -14.7 (2)° for molecule B. In the crystal structure, molecules are arranged in stacks which propagate along the a-axis direction. The crystal structure is stabilized by a number of weak C-H...[pi] interactions.

Online 6 February 2009


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