metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

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ISSN: 2056-9890

Poly[bis­­(cyanato-κN)bis­­(μ-pyrazine-κ2N:N′)cobalt(II)]

aInstitut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, D-24118 Kiel, Germany
*Correspondence e-mail: mwriedt@ac.uni-kiel.de

(Received 16 February 2009; accepted 17 February 2009; online 25 March 2009)

In the crystal structure of the title compound, [Co(NCO)2(C4H4N2)2]n, the Co(II) cation is coordinated by four N-bonded pyrazine ligands and two N-bonded cyanate anions in a slightly distorted octa­hedral geometry. The crystal structure consists of μ-N:N′ pyrazine-bridged cobalt cyanate chains; these are further linked by additional μ-N:N′-bridging pyrazine ligands into layers, which are stacked perpendicular to the crystallographic a axis. The C and O atoms in both crystallographic independent cyanate anions are disordered in two orientations and were refined using a split model with site occupation factor ratios of 0.75/0.25 and 0.7/0.3.

Related literature

For related pyrazine structures, see: Lloret et al. (1999[Lloret, F., Julve, M., Cano, J. & Munno, G. D. (1999). Mol. Cryst. Liq. Cryst. 334, 569-585.]); Real et al. (1991[Real, J. A., Munno, G. D., Munoz, M. C. & Julve, M. (1991). Inorg. Chem. 30, 2701-2704.]); Lu et al. (1997[Lu, J., Paliwala, T., Lim, S. C., Yu, C., Niu, T. & Jacobson, A. J. (1997). Inorg. Chem. 36, 923-929.]); Wriedt et al. (2009[Wriedt, M., Jess, I. & Näther, C. (2009). Eur. J. Inorg. Chem. In the press. ]). For general background, see: Näther & Greve (2003[Näther, C. & Greve, J. (2003). J. Solid State Chem. 176, 259-265.]); Näther et al. (2003[Näther, C., Wriedt, M. & Jess, I. (2003). Inorg. Chem. 42, 2391-2397.]); Wriedt et al. (2008[Wriedt, M., Jess, I. & Näther, C. (2008). Eur. J. Inorg. Chem. pp. 363-372.], 2009[Wriedt, M., Jess, I. & Näther, C. (2009). Eur. J. Inorg. Chem. In the press. ]); Näther et al. (2007[Näther, C., Bhosekar, G. & Jess, I. (2007). Eur. J. Inorg. Chem. pp. 5353-5359.]); Näther & Jess (2004[Näther, C. & Jess, I. (2004). Eur. J. Inorg. Chem. pp. 2868-2876.]).

[Scheme 1]

Experimental

Crystal data
  • [Co(NCO)2(C4H4N2)2]

  • Mr = 303.15

  • Monoclinic, C 2/c

  • a = 25.5712 (17) Å

  • b = 10.1230 (8) Å

  • c = 10.1863 (7) Å

  • β = 104.763 (8)°

  • V = 2549.8 (3) Å3

  • Z = 8

  • Mo Kα radiation

  • μ = 1.35 mm−1

  • T = 170 K

  • 0.24 × 0.14 × 0.07 mm

Data collection
  • Stoe IPDS-1 diffractometer

  • Absorption correction: numerical (X-SHAPE and X-RED32; Stoe & Cie, 2008[Stoe & Cie (2008). X-AREA, X-RED32 and X-SHAPE. Stoe & Cie, Darmstadt, Germany.]) Tmin = 0.789, Tmax = 0.903

  • 11369 measured reflections

  • 2684 independent reflections

  • 2058 reflections with I > 2σ(I)

  • Rint = 0.039

Refinement
  • R[F2 > 2σ(F2)] = 0.051

  • wR(F2) = 0.139

  • S = 1.04

  • 2684 reflections

  • 198 parameters

  • H-atom parameters constrained

  • Δρmax = 0.71 e Å−3

  • Δρmin = −1.17 e Å−3

Table 1
Selected geometric parameters (Å, °)

Co1—N21 2.039 (3)
Co1—N31 2.059 (3)
Co1—N11 2.191 (3)
Co1—N2i 2.193 (3)
Co1—N12ii 2.197 (3)
Co1—N1 2.200 (3)
Symmetry codes: (i) [x, -y+1, z-{\script{1\over 2}}]; (ii) [x, -y+2, z+{\script{1\over 2}}].

Data collection: X-AREA (Stoe & Cie, 2008[Stoe & Cie (2008). X-AREA, X-RED32 and X-SHAPE. Stoe & Cie, Darmstadt, Germany.]); cell refinement: X-AREA; data reduction: X-AREA; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: XP in SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: XCIF in SHELXTL.

Supporting information


Comment top

In our investigations we have recently demonstrated that new ligand deficient coordination polymers with interestic magnetic properties can be prepared by thermal decomposition of suitable ligand rich precursor compounds (Näther & Greve, 2003; Wriedt et al., 2009). In order to prepare additional ligand rich precursor compounds we have reacted cobalt(II) nitrate hexahydrate and potassium cyanate with pyrazine in a methanol water mixture. In this reaction single crystals of the title compound were obtained in an inhomogenous mixture containing additional unknown phases.

In the crystal structure of the 1:2 title compound [Co(OCN)2(pyrazine)2]n the cobalt(II) cations are coordinated by four pyrazine ligands and two thiocyanate anions within slightly distorted octahedra (Fig. 1). The cobalt cations are µ-1,4-(N,N) bridged by the pyrazine ligands forming layers, which are stacked perpendicular to the crystallographic a-axis (Fig. 2). The cyanate anions do not act as bridging ligands and are only terminal N-bonded to the metal center. A similar structural motif is observed in the structures of the 1:2 thiocyanate compounds of composition [M(SCN)2(pyrazine)2]n (M = Mn, Fe, Co, Ni) reported recently (Lloret et al., 1999; Real et al., 1991; Lu et al.., 1997; Wriedt et al., 2009). The Co—NCO distances amount to 2.039 (3) and 2.059 (3) Å and are significantly shorter as the Co—Npyrazine distances, which range from 2.191 (3) to 2.200 (3) Å. The angles around the cobalt cations range between 89.23 (12) and 179.58 (12)° (Tab. 1). The shortest intra- and interchain Co···Co distances amount to 7.1721 (4) and 8.2170 (5) Å, respectively.

Related literature top

For related pyrazine structures, see: Lloret et al. (1999); Real et al. (1991); Lu et al. (1997); Wriedt et al. (2009). For general background, see: Näther & Greve (2003); Näther et al. (2003); Wriedt et al. (2008, 2009); Näther et al. (2007); Näther & Jeß (2004).

Experimental top

Co(NO3)2.6H2O, pyrazine and methanol were obtained from Alfa Aesar as well as KOCN was obtained from Fluka. 0.5 mmol (145.5 mg) Co(NO3)2.6H2O, 1 mmol (81.1 mg) KOCN, 0.5 mmol (40.1 mg) pyrazine, 0.5 mL methanol and 0.5 mL water were transfered in a closed test-tube. The mixture was heated at 120 °C for three days. After cooling yellow block-shaped single crystals of the title compound were obtained in a heterogenous mixture.

Refinement top

All H atoms were located in a difference map but they were positioned with idealized geometry and were refined with Ueq(H) = 1.2 Ueq(C) using a riding model with C—H = 0.95 Å.

The C and O atoms in both crystallographic independent cyanate anions are disordered in two orientations and were refined using a split model. In one of the two anions, the C and O atoms of lower occupancy were refined only isotropically. They were refined by a split model with site occupation factor ratios of 0.75/0.25 and 0.7/0.3.

Computing details top

Data collection: X-AREA (Stoe & Cie, 2008); cell refinement: X-AREA (Stoe & Cie, 2008); data reduction: X-AREA (Stoe & Cie, 2008); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: XP in SHELXTL (Sheldrick, 2008); software used to prepare material for publication: XCIF in SHELXTL (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. Crystal structure of the title compound with labelling and displacement ellipsoids drawn at the 50% probability level. The disorder of the cyanate anions is not show for clarity. [Symmetry codes: (i) x, -y+1, z-1/2; (ii) x, -y+2, z+1/2.]
[Figure 2] Fig. 2. Crystal structure of the title compound with view along the a-axis.
Poly[bis(cyanato-κN)bis(µ-pyrazine-κ2N:N')cobalt(II)] top
Crystal data top
[Co(NCO)2(C4H4N2)2]F(000) = 1224
Mr = 303.15Dx = 1.579 Mg m3
Monoclinic, C2/cMo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2ycCell parameters from 8000 reflections
a = 25.5712 (17) Åθ = 14.1–25.9°
b = 10.1230 (8) ŵ = 1.35 mm1
c = 10.1863 (7) ÅT = 170 K
β = 104.763 (8)°Block, yellow
V = 2549.8 (3) Å30.24 × 0.14 × 0.07 mm
Z = 8
Data collection top
Stoe IPDS-1
diffractometer
2684 independent reflections
Radiation source: fine-focus sealed tube2058 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.039
ϕ scansθmax = 27.1°, θmin = 2.9°
Absorption correction: numerical
(X-SHAPE and X-RED32; Stoe & Cie, 2008)
h = 3232
Tmin = 0.789, Tmax = 0.903k = 1212
11369 measured reflectionsl = 1313
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.051Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.139H-atom parameters constrained
S = 1.04 w = 1/[σ2(Fo2) + (0.0575P)2 + 18.631P]
where P = (Fo2 + 2Fc2)/3
2684 reflections(Δ/σ)max = 0.001
198 parametersΔρmax = 0.71 e Å3
0 restraintsΔρmin = 1.17 e Å3
Crystal data top
[Co(NCO)2(C4H4N2)2]V = 2549.8 (3) Å3
Mr = 303.15Z = 8
Monoclinic, C2/cMo Kα radiation
a = 25.5712 (17) ŵ = 1.35 mm1
b = 10.1230 (8) ÅT = 170 K
c = 10.1863 (7) Å0.24 × 0.14 × 0.07 mm
β = 104.763 (8)°
Data collection top
Stoe IPDS-1
diffractometer
2684 independent reflections
Absorption correction: numerical
(X-SHAPE and X-RED32; Stoe & Cie, 2008)
2058 reflections with I > 2σ(I)
Tmin = 0.789, Tmax = 0.903Rint = 0.039
11369 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0510 restraints
wR(F2) = 0.139H-atom parameters constrained
S = 1.04 w = 1/[σ2(Fo2) + (0.0575P)2 + 18.631P]
where P = (Fo2 + 2Fc2)/3
2684 reflectionsΔρmax = 0.71 e Å3
198 parametersΔρmin = 1.17 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Co10.629290 (19)0.75059 (4)0.63502 (4)0.01326 (17)
N10.62838 (13)0.5943 (3)0.7846 (3)0.0162 (6)
C10.66193 (17)0.5983 (3)0.9072 (4)0.0224 (8)
H10.68680.66950.92970.027*
C20.66194 (17)0.5014 (4)1.0044 (3)0.0224 (8)
H20.68640.50881.09160.027*
N20.62829 (13)0.3981 (3)0.9778 (3)0.0171 (6)
C30.59444 (17)0.3935 (4)0.8537 (3)0.0230 (8)
H30.57000.32150.83050.028*
C40.59412 (17)0.4920 (4)0.7578 (4)0.0225 (8)
H40.56900.48640.67140.027*
N110.63140 (13)0.9093 (3)0.4902 (3)0.0163 (6)
C110.67047 (17)0.9151 (4)0.4247 (4)0.0228 (8)
H110.69920.85280.44610.027*
C120.67008 (17)1.0102 (3)0.3260 (4)0.0222 (8)
H120.69841.01100.28100.027*
N120.63094 (13)1.1005 (3)0.2930 (3)0.0167 (6)
C130.59214 (17)1.0958 (4)0.3588 (4)0.0259 (9)
H130.56371.15900.33810.031*
C140.59239 (18)1.0000 (4)0.4575 (4)0.0259 (9)
H140.56410.99930.50250.031*
N210.54684 (14)0.7557 (3)0.5817 (3)0.0238 (7)
C210.5047 (3)0.7083 (8)0.5445 (8)0.0347 (16)0.75
O210.4602 (3)0.6596 (9)0.5110 (10)0.109 (4)0.75
O21'0.4627 (6)0.7506 (17)0.4184 (18)0.052 (4)0.25
C21'0.5054 (9)0.7583 (16)0.498 (2)0.023 (4)0.25
N310.71251 (14)0.7443 (3)0.6873 (3)0.0218 (7)
C310.7539 (3)0.7288 (7)0.7698 (8)0.0250 (15)0.70
O310.7962 (3)0.7135 (8)0.8513 (7)0.074 (3)0.70
C31'0.7530 (9)0.7621 (19)0.734 (2)0.030 (6)*0.30
O31'0.8018 (11)0.771 (2)0.789 (3)0.098 (8)*0.30
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Co10.0272 (3)0.0060 (2)0.0076 (2)0.00033 (18)0.00627 (18)0.00004 (16)
N10.0307 (18)0.0095 (13)0.0085 (13)0.0035 (11)0.0050 (13)0.0015 (10)
C10.037 (2)0.0124 (16)0.0150 (16)0.0096 (15)0.0022 (16)0.0021 (13)
C20.037 (2)0.0160 (17)0.0103 (15)0.0053 (15)0.0003 (16)0.0024 (13)
N20.0319 (18)0.0090 (13)0.0093 (13)0.0019 (11)0.0033 (13)0.0010 (10)
C30.039 (2)0.0161 (17)0.0119 (16)0.0099 (15)0.0021 (16)0.0006 (13)
C40.036 (2)0.0161 (17)0.0110 (15)0.0066 (15)0.0009 (16)0.0028 (13)
N110.0312 (18)0.0083 (13)0.0119 (13)0.0028 (11)0.0100 (13)0.0027 (10)
C110.036 (2)0.0137 (17)0.0241 (18)0.0075 (15)0.0172 (17)0.0096 (14)
C120.036 (2)0.0147 (16)0.0220 (17)0.0080 (15)0.0182 (17)0.0087 (14)
N120.0331 (18)0.0079 (13)0.0129 (14)0.0033 (11)0.0126 (14)0.0015 (10)
C130.041 (2)0.0177 (18)0.0257 (19)0.0137 (16)0.0198 (19)0.0117 (15)
C140.039 (2)0.0179 (18)0.0278 (19)0.0093 (16)0.0216 (18)0.0111 (15)
N210.0311 (18)0.0192 (16)0.0204 (15)0.0023 (14)0.0056 (16)0.0001 (12)
C210.034 (4)0.032 (4)0.040 (4)0.000 (3)0.014 (3)0.027 (3)
O210.041 (4)0.137 (8)0.152 (8)0.033 (4)0.031 (5)0.114 (7)
O21'0.027 (7)0.061 (11)0.055 (9)0.012 (7)0.016 (8)0.038 (8)
C21'0.040 (12)0.004 (8)0.023 (9)0.001 (7)0.003 (9)0.004 (6)
N310.0318 (18)0.0171 (16)0.0183 (15)0.0012 (13)0.0099 (15)0.0002 (12)
C310.038 (4)0.018 (3)0.016 (3)0.007 (3)0.001 (3)0.010 (3)
O310.052 (4)0.089 (5)0.055 (4)0.036 (4)0.031 (4)0.053 (4)
Geometric parameters (Å, º) top
Co1—N212.039 (3)N11—C111.337 (5)
Co1—N312.059 (3)C11—C121.390 (5)
Co1—N112.191 (3)C11—H110.9500
Co1—N2i2.193 (3)C12—N121.333 (5)
Co1—N12ii2.197 (3)C12—H120.9500
Co1—N12.200 (3)N12—C131.332 (5)
N1—C11.324 (5)N12—Co1iv2.197 (3)
N1—C41.339 (5)C13—C141.397 (5)
C1—C21.394 (5)C13—H130.9500
C1—H10.9500C14—H140.9500
C2—N21.337 (5)N21—C211.151 (8)
C2—H20.9500N21—C21'1.18 (2)
N2—C31.338 (5)C21—O211.206 (9)
N2—Co1iii2.193 (3)O21'—C21'1.19 (3)
C3—C41.395 (5)N31—C31'1.04 (2)
C3—H30.9500N31—C311.182 (8)
C4—H40.9500C31—O311.195 (9)
N11—C141.334 (5)C31'—O31'1.24 (4)
N21—Co1—N31179.45 (13)N1—C4—H4119.2
N21—Co1—N1190.19 (12)C3—C4—H4119.2
N31—Co1—N1189.76 (12)C14—N11—C11116.8 (3)
N21—Co1—N2i90.23 (12)C14—N11—Co1121.8 (2)
N31—Co1—N2i89.23 (12)C11—N11—Co1121.2 (2)
N11—Co1—N2i90.53 (11)N11—C11—C12121.5 (3)
N21—Co1—N12ii90.19 (12)N11—C11—H11119.2
N31—Co1—N12ii90.35 (12)C12—C11—H11119.2
N11—Co1—N12ii89.45 (10)N12—C12—C11121.6 (3)
N2i—Co1—N12ii179.58 (12)N12—C12—H12119.2
N21—Co1—N190.57 (12)C11—C12—H12119.2
N31—Co1—N189.49 (12)C13—N12—C12117.1 (3)
N11—Co1—N1178.55 (11)C13—N12—Co1iv121.0 (2)
N2i—Co1—N190.70 (10)C12—N12—Co1iv121.9 (2)
N12ii—Co1—N189.32 (10)N12—C13—C14121.3 (3)
C1—N1—C4116.7 (3)N12—C13—H13119.3
C1—N1—Co1120.9 (2)C14—C13—H13119.3
C4—N1—Co1122.5 (2)N11—C14—C13121.6 (3)
N1—C1—C2122.1 (3)N11—C14—H14119.2
N1—C1—H1118.9C13—C14—H14119.2
C2—C1—H1118.9C21—N21—C21'34.7 (8)
N2—C2—C1121.5 (3)C21—N21—Co1153.4 (5)
N2—C2—H2119.3C21'—N21—Co1150.6 (11)
C1—C2—H2119.3N21—C21—O21177.2 (8)
C2—N2—C3116.5 (3)N21—C21'—O21'174 (2)
C2—N2—Co1iii120.1 (2)C31'—N31—C3124.8 (10)
C3—N2—Co1iii123.4 (2)C31'—N31—Co1163.3 (12)
N2—C3—C4121.6 (3)C31—N31—Co1150.1 (5)
N2—C3—H3119.2N31—C31—O31178.7 (10)
C4—C3—H3119.2N31—C31'—O31'174 (2)
N1—C4—C3121.6 (3)
Symmetry codes: (i) x, y+1, z1/2; (ii) x, y+2, z+1/2; (iii) x, y+1, z+1/2; (iv) x, y+2, z1/2.

Experimental details

Crystal data
Chemical formula[Co(NCO)2(C4H4N2)2]
Mr303.15
Crystal system, space groupMonoclinic, C2/c
Temperature (K)170
a, b, c (Å)25.5712 (17), 10.1230 (8), 10.1863 (7)
β (°) 104.763 (8)
V3)2549.8 (3)
Z8
Radiation typeMo Kα
µ (mm1)1.35
Crystal size (mm)0.24 × 0.14 × 0.07
Data collection
DiffractometerStoe IPDS1
diffractometer
Absorption correctionNumerical
(X-SHAPE and X-RED32; Stoe & Cie, 2008)
Tmin, Tmax0.789, 0.903
No. of measured, independent and
observed [I > 2σ(I)] reflections
11369, 2684, 2058
Rint0.039
(sin θ/λ)max1)0.641
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.051, 0.139, 1.04
No. of reflections2684
No. of parameters198
H-atom treatmentH-atom parameters constrained
w = 1/[σ2(Fo2) + (0.0575P)2 + 18.631P]
where P = (Fo2 + 2Fc2)/3
Δρmax, Δρmin (e Å3)0.71, 1.17

Computer programs: X-AREA (Stoe & Cie, 2008), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), XP in SHELXTL (Sheldrick, 2008), XCIF in SHELXTL (Sheldrick, 2008).

Selected geometric parameters (Å, º) top
Co1—N212.039 (3)Co1—N2i2.193 (3)
Co1—N312.059 (3)Co1—N12ii2.197 (3)
Co1—N112.191 (3)Co1—N12.200 (3)
N21—Co1—N31179.45 (13)N11—Co1—N12ii89.45 (10)
N21—Co1—N1190.19 (12)N2i—Co1—N12ii179.58 (12)
N31—Co1—N1189.76 (12)N21—Co1—N190.57 (12)
N21—Co1—N2i90.23 (12)N31—Co1—N189.49 (12)
N31—Co1—N2i89.23 (12)N11—Co1—N1178.55 (11)
N11—Co1—N2i90.53 (11)N2i—Co1—N190.70 (10)
N21—Co1—N12ii90.19 (12)N12ii—Co1—N189.32 (10)
N31—Co1—N12ii90.35 (12)
Symmetry codes: (i) x, y+1, z1/2; (ii) x, y+2, z+1/2.
 

Acknowledgements

MW thanks the Stiftung Stipendien-Fonds des Verbandes der Chemischen Industrie and the Studienstiftung des deutschen Volkes for a PhD scholarship. We gratefully acknowledge financial support by the State of Schleswig-Holstein and we thank Professor Dr Wolfgang Bensch for the opportunity to use his experimental facility.

References

First citationLloret, F., Julve, M., Cano, J. & Munno, G. D. (1999). Mol. Cryst. Liq. Cryst. 334, 569–585.  Web of Science CrossRef CAS Google Scholar
First citationLu, J., Paliwala, T., Lim, S. C., Yu, C., Niu, T. & Jacobson, A. J. (1997). Inorg. Chem. 36, 923–929.  CSD CrossRef CAS Web of Science Google Scholar
First citationNäther, C., Bhosekar, G. & Jess, I. (2007). Eur. J. Inorg. Chem. pp. 5353–5359.  Google Scholar
First citationNäther, C. & Greve, J. (2003). J. Solid State Chem. 176, 259–265.  Google Scholar
First citationNäther, C. & Jess, I. (2004). Eur. J. Inorg. Chem. pp. 2868–2876.  Google Scholar
First citationNäther, C., Wriedt, M. & Jess, I. (2003). Inorg. Chem. 42, 2391–2397.  Web of Science CSD CrossRef PubMed Google Scholar
First citationReal, J. A., Munno, G. D., Munoz, M. C. & Julve, M. (1991). Inorg. Chem. 30, 2701–2704.  CSD CrossRef CAS Web of Science Google Scholar
First citationSheldrick, G. M. (2008). Acta Cryst. A64, 112–122.  Web of Science CrossRef CAS IUCr Journals Google Scholar
First citationStoe & Cie (2008). X-AREA, X-RED32 and X-SHAPE. Stoe & Cie, Darmstadt, Germany.  Google Scholar
First citationWriedt, M., Jess, I. & Näther, C. (2008). Eur. J. Inorg. Chem. pp. 363–372.  Google Scholar
First citationWriedt, M., Jess, I. & Näther, C. (2009). Eur. J. Inorg. Chem. In the press.  Google Scholar

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