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Acta Cryst. (2009). E65, m460  [ doi:10.1107/S1600536809011076 ]

Di-[mu]-chlorido-bis{aquachlorido[2,2'-thiobis(pyridine N-oxide)-[kappa]O]copper(II)}

R. W. Seidel and I. M. Oppel

Abstract: The crystal structure of the title compound, [Cu2Cl4(C10H8N2O2S)2(H2O)2], comprises neutral centrosymmetric [mu]-chloride-bridged dinuclear units. Each CuII ion is pentacoordinated by three chloride ligands, a pyridine N-oxide O atom and a water molecule. Intra- and intermolecular O-H...O hydrogen bonds occur between the coordinated water molecules and the uncoordinated and coordinated pyridine N-oxide groups of the 2,2'-thiobis(pyridine N-oxide) ligands, respectively.

Online 28 March 2009


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