Acta Cryst. (2009). E65, m435  [ doi:10.1107/S1600536809009003 ]

Bis[-N'-isobutyryl-1-oxidonaphthalene-2-carbohydrazidato(3-)]dipyridinetricopper(II)

X.-F. Shi, D. Li, P.-Y. Li and D.-Q. Wang

Abstract: The complete molecule of the title complex, [Cu₃(C₁₅H₁₃N₂O₃)₂(C₅H₅N)₂], is generated by crystallographic twofold symmetry, with the central Cu atom lying on the rotation axis: it is coordinated by two N,O-bidentate ligands in a trans-CuN₂O₂ distorted square-planar arrangement. The other Cu atom is coordinated by an N,O,O'-tridentate ligand and a pyridine molecule in a distorted trans-CuN₂O₂ arrangement. In the crystal structure, a C-H interaction occurs.

Online 25 March 2009

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