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Acta Cryst. (2009). E65, m462-m463  [ doi:10.1107/S160053680901099X ]

Di-[mu]-iodido-bis{[dicyclohexyl(phenyl)phosphine-[kappa]P](pyridine-[kappa]N)silver(I)}

B. Omondi and R. Meijboom

Abstract: The title compound, [Ag2I2(C5H5N)2(C18H27P)2], contains centrosymmetric dinuclear species in which each Ag atom is surrounded by a phosphine ligand, a weakly coordinating pyridine ligand and two iodide anions in a distorted tetrahedral coordination. The two iodide anions bridge the Ag atoms, which are separated by a distance of 3.1008 (6) Å. The Ag-P distance is 2.4436 (8) Å, Ag-N is 2.386 (3)Å and the Ag-I distances are 2.8186 (4) and 2.9449 (5) Å.

Online 31 March 2009


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