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Acta Cryst. (2009). E65, m385  [ doi:10.1107/S1600536809007910 ]

Phyllo-poly[[[mu]2-1,4-bis(cyclohexylsulfanylmethyl)benzene-[kappa]2S:S']([mu]2-nitrato-[kappa]2O:O')silver(I)]

T. H. Kim, Y. W. Shin, K.-M. Park and J. Kim

Abstract: The title compound, [Ag(NO3)(C20H30S2)]n, was synthesized by the reaction of silver nitrate and 1,4-bis(cyclohexylthiomethyl)benzene (bctmb) in acetonitrile. The coordination polymer exhibits a two-dimensional layer structure. The layers are wave-like and parallel to the crystallographic ac plane; AgI ions are linked by the bctmb ligands and nitrate anions along the crystallographic a and c directions, respectively. In addition, the crystal structure is stabilized by C-H...O hydrogen bonds.

Online 11 March 2009


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