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Acta Cryst. (2009). E65, m398-m399  [ doi:10.1107/S1600536809008393 ]

Dicyclohexyl[N-(3-methoxy-2-oxidobenzylidene)valinato-[kappa]3O,N,O']tin(IV)

H.-J. Yang and Y.-Q. Dang

Abstract: In the title compound, [Sn(C6H11)2(C13H15NO4)], the Sn atom is five-coordinate and adopts a distorted trigonal-bipyramidal SnNC2O2 geometry with the O atoms in axial positions. The metal atom forms five- and six-membered chelate rings with the O,N,O'-tridentate ligand. The two cyclohexyl groups bound to the Sn atom adopt chair conformations, with the Sn-C bonds in equatorial positions and a mean Sn-C distance of 2.138 (3) Å.

Online 14 March 2009


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