Acta Cryst. (2009). E65, m373-m374  [ doi:10.1107/S1600536809007363 ]

Bis(ferrocenecarbaldehyde thiosemicarbazonato-²N¹,S)zinc

M. R. Vikneswaran, S. G. Teoh, I. A. Razak and H.-K. Fun

Abstract: In the title compound, [Fe₂Zn(C₅H₅)₂(C₇H₇N₃S)₂], the Cp rings of each ferrocene residue have a nearly eclipsed conformation. The two thiosemicarbazone ligands each coordinate the Zn atom in a bidentate mode via the N and S atoms, thereby defining a distorted tetrahedral environment. N-HS, N-HN, C-HS and C-HN intra- and intermolecular interactions connect the molecules into a two-dimensional array parallel to (010).

Online 6 March 2009

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