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Volume 65 
Part 4 
Page m416  
April 2009  

Received 27 February 2009
Accepted 12 March 2009
Online 19 March 2009

Key indicators
Single-crystal X-ray study
T = 293 K
Mean [sigma](C-C) = 0.004 Å
R = 0.032
wR = 0.082
Data-to-parameter ratio = 12.4
Details
Open access

Poly[bis([mu]3-5-nitroisophthalato)bis(1,10-phenanthroline)dimanganese(II)]

aBiological and Chemical Engineering School, Jiaxing University, Jiaxing 314001, People's Republic of China, and bCollege of Chemistry, Beijing Normal University, Beijing, People's Republic of China
Correspondence e-mail: hhy123@163.com

The title complex, [Mn2(C8H3NO6)2(C12H8N2)2]n, was synthesized under hydrothermal conditions. The structure contains two independent MnII atoms, each coordinated in a distorted octahedral MnN2O4 geometry. [Mn2(phen)2] units (phen = 1,10-phenantroline) are bridged by 5-nitroisophthalate (nip) ligands into ladder-like chains parallel to [100]. Adjacent polymeric chains are linked by C-H...O and [pi]-[pi] interactions [centroid-to-centroid distance = 3.6369 (12) Å] into a two-dimensional framework parallel to (010).

Related literature

For related isophthalate complexes, see: He et al. (2004[He, H.-Y., Zhou, Y.-L. & Zhu, L.-G. (2004). Acta Cryst. C60, m569-m571.], 2005[He, H.-Y., Zhou, Y.-L., Hong, Y. & Zhu, L.-G. (2005). J. Mol. Struct. 737, 97-101.]); Sun et al. (2003[Sun, D., Cao, R., Sun, Y., Li, X., Bi, W., Hong, M. & Zhao, Y. (2003). Eur. J. Inorg. Chem. pp. 94-98.]); Wu et al. (2002[Wu, C.-D., Lu, C.-Z., Yang, W.-B., Zhuang, H.-H. & Huang, J.-S. (2002). Inorg. Chem. 41, 3302-3307.]).

[Scheme 1]

Experimental

Crystal data
  • [Mn2(C8H3NO6)2(C12H8N2)2]

  • Mr = 888.52

  • Triclinic, [P \overline 1]

  • a = 10.0602 (1) Å

  • b = 14.3435 (2) Å

  • c = 14.6637 (2) Å

  • [alpha] = 104.052 (1)°

  • [beta] = 102.633 (1)°

  • [gamma] = 110.460 (1)°

  • V = 1812.69 (4) Å3

  • Z = 2

  • Mo K[alpha] radiation

  • [mu] = 0.78 mm-1

  • T = 293 K

  • 0.28 × 0.23 × 0.19 mm

Data collection
  • Bruker SMART CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2002[Bruker (2002). SADABS, SAINT and SMART. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.82, Tmax = 0.90

  • 19255 measured reflections

  • 6733 independent reflections

  • 5771 reflections with I > 2[sigma](I)

  • Rint = 0.021

Refinement
  • R[F2 > 2[sigma](F2)] = 0.032

  • wR(F2) = 0.082

  • S = 1.05

  • 6733 reflections

  • 541 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.38 e Å-3

  • [Delta][rho]min = -0.28 e Å-3

Table 1
Selected bond lengths (Å)

Mn1-O6i 2.1498 (15)
Mn1-O11 2.1508 (15)
Mn1-N2 2.2531 (18)
Mn1-N1 2.2584 (18)
Mn1-O1 2.2661 (15)
Mn1-O2 2.2879 (15)
Mn2-O5 2.1608 (15)
Mn2-O12ii 2.1652 (15)
Mn2-O7 2.1938 (16)
Mn2-N5 2.2411 (18)
Mn2-N6 2.2697 (19)
Mn2-O8 2.3830 (16)
Symmetry codes: (i) x+1, y, z; (ii) x-1, y, z.

Table 2
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
C3-H3...O1iii 0.93 2.50 3.267 (4) 140
C10-H10...O2iv 0.93 2.54 3.210 (3) 129
C29-H29...O5 0.93 2.51 3.079 (3) 119
C31-H31...O3v 0.93 2.38 2.888 (4) 114
C38-H38...O7vi 0.93 2.45 3.121 (3) 129
C38-H38...O12vii 0.93 2.60 3.351 (3) 139
Symmetry codes: (iii) -x+1, -y+1, -z+1; (iv) -x+1, -y, -z+1; (v) x, y+1, z; (vi) -x-1, -y, -z; (vii) -x, -y, -z.

Data collection: SMART (Bruker, 2002[Bruker (2002). SADABS, SAINT and SMART. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2002[Bruker (2002). SADABS, SAINT and SMART. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997[Farrugia, L. J. (1997). J. Appl. Cryst. 30, 565.]); software used to prepare material for publication: PLATON (Spek, 2009[Spek, A. L. (2009). Acta Cryst. D65, 148-155.]).


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: WM2223 ).


References

Bruker (2002). SADABS, SAINT and SMART. Bruker AXS Inc., Madison, Wisconsin, USA.
Farrugia, L. J. (1997). J. Appl. Cryst. 30, 565.  [CrossRef] [details]
He, H.-Y., Zhou, Y.-L., Hong, Y. & Zhu, L.-G. (2005). J. Mol. Struct. 737, 97-101.  [ISI] [CSD] [CrossRef] [ChemPort]
He, H.-Y., Zhou, Y.-L. & Zhu, L.-G. (2004). Acta Cryst. C60, m569-m571.  [CrossRef] [details]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Spek, A. L. (2009). Acta Cryst. D65, 148-155.  [ISI] [CrossRef] [details]
Sun, D., Cao, R., Sun, Y., Li, X., Bi, W., Hong, M. & Zhao, Y. (2003). Eur. J. Inorg. Chem. pp. 94-98.  [CSD] [CrossRef]
Wu, C.-D., Lu, C.-Z., Yang, W.-B., Zhuang, H.-H. & Huang, J.-S. (2002). Inorg. Chem. 41, 3302-3307.  [ISI] [CSD] [CrossRef] [PubMed] [ChemPort]


Acta Cryst (2009). E65, m416  [ doi:10.1107/S1600536809009052 ]

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