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Acta Cryst. (2009). E65, m510  [ doi:10.1107/S1600536809012562 ]

Poly[di-[mu]2-acetato-diaquabis(2,2'-bipyridine)bis([mu]3-5-nitroisophthalato)tricobalt(II)]

H.-D. Wang, M.-M. Li and H.-Y. He

Abstract: The title complex, [Co3(C8H3NO6)2(C2H3O2)2(C10H8N2)2(H2O)2], was synthesized under hydrothermal conditions. The structure features a centrosymmetric complex with three CoII centres, one of which is located on a centre of inversion. The Co centres are coordinated in a distorted octahedral geometry. The bipyridine ligands are bonded to just one Co centre in a chelating mode, whereas the 5-nitroisophthalate and acetate ions are bonded to two different Co atoms. The crystal structure is stabilized by O-H...O hydrogen bonds.

Online 10 April 2009


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