Acta Cryst. (2009). E65, m507  [ doi:10.1107/S1600536809012975 ]

Poly[₂-chlorido-(₂-3H⁺-1,3,4-thiadiazolium-2-thiolato-²S:S)silver(I)]

J.-G. Wang, J.-H. Qin and P.-Z. Hu

Abstract: In the title compound, [AgCl(C₂H₂N₂S₂)]_n, the Ag^I ion has a distorted tetrahedral geometry, defined by two S atoms of two symmetry-related 1,3,4-thiadiazolium-2-thiolate ligands and two chloride ions. The Ag^I ions are bridged into a two-dimensional network parallel to the ab plane by chloride ions and thiadiazole ligands. In the network, the Ag^I ions are separated by 4.0316 (12) Å along the a axis and by 4.8822 (13) Å along the b axis. N-HCl hydrogen bonds are observed within the network.

Online 10 April 2009

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