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Acta Cryst. (2009). E65, m597-m598  [ doi:10.1107/S160053680901486X ]

[[mu]-N,N,N',N'-Tetrakis(diphenylphosphinomethyl)benzene-1,4-diamine-[kappa]4P,P':P'',P''']bis[bis(nitrato-[kappa]O)palladium(II)]

X.-F. Jiang, H.-C. Lian, Z. Min, X.-J. Wang and J.-H. Lin

Abstract: The asymmetric unit of the title complex, [Pd2(NO3)4(C58H52N2P4)], contains one half-molecule, in which the central benzene ring is located on a crystallographic centre of inversion. The Pd atom has a distorted square-planar coordination consisting of two P and two O atoms. In the crystal structure, intermolecular C-H...O interactions link the molecules into chains, and [pi]-[pi] contacts between the phenyl rings [centroid-centroid distance = 3.928 (3) Å] may further stabilize the structure.

Online 30 April 2009


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