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Acta Cryst. (2009). E65, o1009-o1010  [ doi:10.1107/S1600536809012677 ]

N'-[(2Z)-3-Allyl-4-oxo-1,3-thiazolidin-2-ylidene]-5-fluoro-3-phenyl-1H-indole-2-carbohydrazide

M. Akkurt, S. Karaca, G. Cihan, G. Çapan and O. Büyükgüngör

Abstract: In the title compound, C21H17FN4O2S, the planar indole fused-ring [maximum deviation 0.009 (1) Å] makes dihedral angles of 54.75 (9) and 14.90 (9)°, respectively, with the phenyl ring and the dihydrothiazolyl ring. The -CH2CH=CH2 substituent is disordered over two positions in a 0.51 (1):0.49 (1) ratio. An intramolecular N-H...S hydrogen bond generates an S(5) ring motif. The two independent molecules are linked into a dimer by two N-H...O hydrogen bonds, forming an R22(10) ring motif. The crystal structure features intermolecular C-H...[pi] and [pi]-[pi] stacking [centroid-centroid distance = 3.679 (1) Å] interactions. C-H...O and C-H...F interactions are also present.

Online 8 April 2009


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