Acta Cryst. (2009). E65, m529-m530  [ doi:10.1107/S1600536809012884 ]

Bromido{dicyclohexyl[2'-(dimethylamino)biphenyl-2-yl]phosphine-P}[2-(4,6-dimethylpyrimidin-2-yl)ferrocenyl-²C¹,N]palladium(II) dichloromethane solvate

X.-Q. Hao, H.-M. Li, H. Jiang, Y.-T. Ma and M.-P. Song

Abstract: In the title compound, [FePdBr(C₅H₅)(C₁₁H₁₀N₂)(C₂₆H₃₆NP)]·CH₂Cl₂, the Pd atom displays a distorted square-planar coordination environment. The five-membered metallacycle adopts an envelope conformation with the coordinated cyclopentadienyl C atom 0.4222 (4) Å out of plane. The dihedral angle between the pyrimidinyl ring and substituted cyclopentadienyl ring is 21.47 (2)°. In the crystal structure, the dimeric unit is generated through the C-H contact via a crystallographic inversion centre, while the C-HCl contacts in the dimeric centre link the dichlormethane molecules with the Pd complex molecules.

Online 18 April 2009

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