[HTML version][PDF version][CIF][3d view][Structure Factors][Supplementary Material][CIF check Report][Issue contents]  [Open access]

[Contents scheme]

Acta Cryst. (2009). E65, o1029  [ doi:10.1107/S1600536809012951 ]

Ethyl 2-[(4-chlorophenyl)hydrazono]-3-oxobutanoate

H.-K. Fun, S. Chantrapromma, M. Padaki, Radhika and A. M. Isloor

Abstract: The molecule of the title oxobutanoate derivative, C12H13ClN2O3, is nearly planar; the interplanar angle between the benzene ring and the mean plane through the hydrazono-3-oxobutanoate unit is 2.69 (3)°. An intramolecular N-H...O hydrogen bond generates an S(6) ring motif. In the crystal packing, C-H...O(3-oxo) interactions link molecules into dimers. The dimers thus formed are linked through C-H...O(carboxylate C=O) interactions, leading to the formation of ribbons along the [01\\overline 1] direction, which are stabilized via Cl...Cl [3.2916 (3) Å] contacts. The ribbons are stacked via C...O contacts [3.2367 (12)-3.3948 (12) Å].

Online 10 April 2009


Copyright © International Union of Crystallography
IUCr Webmaster