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Acta Cryst. (2009). E65, m541  [ doi:10.1107/S1600536809013774 ]

Bis[4-hydroxy-N'-(4-methoxy-2-oxidobenzylidene-[kappa]O2)benzohydrazidato-[kappa]2O,N']cadmium(II) dimethyl sulfoxide disolvate

N. Mohd Lair, H. Mohd Ali and S. W. Ng

Abstract: The metal atom in the title compound, [Cd(C15H13N2O4)2]·2C2H6OS, is twice O,N,O'-chelated by two symmetry-related Schiff base ligands to define a trans-N2O4 octahedral geometry. Each anion occupies meridional sites of the octahedron; the metal atom lies on a special position of site symmetry 2. The dimethyl sulfoxide molecule is a hydrogen-bond acceptor to the -NH- unit, and O-H...O hydrogen bonds link molecules into a supramolecular chain.

Online 22 April 2009


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