Acta Cryst. (2009). E65, m594  [ doi:10.1107/S1600536809014883 ]

Di-n-butylbis(N-n-butyl-N-ethyldithiocarbamato-S)tin(IV)

I. Baba, N. N. Dzulkefli and S. W. Ng

Abstract: The Sn atom in the title compound, [Sn(C₄H₉)₂(C₇H₁₄NS₂)₂], exists in a tetrahedral C₂S₂Sn coordination geometry. The geometry is distorted towards skew-trapezoidal-bipyramidal owing to the proximity of the double-bond S atoms [Sn-S = 2.521 (2) and SnS = 2.933 (2) Å]. The Sn atom lies on a special position of mm2 site symmetry and the tin-bound n-butyl chain is disordered about a mirror plane. The ethyl and n-butyl groups of the dithiocarbamate unit are disordered about another mirror plane.

Online 30 April 2009

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