Acta Cryst. (2009). E65, m675  [ doi:10.1107/S1600536809018522 ]

Redetermination of tetrakis(N,N-diethyldithiocarbamato)tin(IV)

C. K. Y. A. Okio and N. L. Speziali

Abstract: The crystal structure of the title compound, [Sn(C₅H₁₀NS₂)₄], was originally determined by Harreld & Schlemper [Acta Cryst. (1971), B27, 1964-1969] using intensity data estimated from Weissenberg films. In comparison with the previous refinement, the current redetermination reveals anisotropic displacement parameters for all non-H atoms, localization of the H atoms, and higher precision of lattice parameters and interatomic distances. The complex features a distorted S₆ octahedral coordination geometry for tin and a cis disposition of the monodentate dithiocarbamate ligands.

Online 23 May 2009

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