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Acta Cryst. (2009). E65, o1187  [ doi:10.1107/S1600536809016195 ]

6-(1H-Indol-3-yl)-4-phenyl-2,2'-bipyridine-5-carbonitrile

W. Zhu, Y. Xiang and S. Zhu

Abstract: In the molecule of the title compound, C25H16N4, the pyridine rings are oriented at a dihedral angle of 0.92 (3)°, while the dihedral angle between the benzene ring and the adjacent pyridine ring is 56.51 (3)°. In the crystal structure, intermolecular N-H...N hydrogen bonds link the molecules into centrosymmetric dimers, forming R22(16) ring motifs. [pi]-[pi] contacts between the pyridine ring and the indole ring system and between the pyridine rings [centroid-centroid distances = 3.923 (2) and 3.724 (2) Å] may further stabilize the structure. Two weak C-H...[pi] interactions are also present.

Online 7 May 2009


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