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Acta Cryst. (2009). E65, o1307  [ doi:10.1107/S1600536809017632 ]

[1-(1-Adamantylamino)ethylidene]oxonium methanesulfonate

R. Vícha, M. Necas, Z. Kozubková and M. Potácek

Abstract: In the title salt, C12H20NO+·CH3SO3-, the [1-(1-adamantylamino)ethylidene]oxonium cations and methanesulfonate anions are linked into chains along the a axis via O-H...O and N-H...O hydrogen bonds. All non-H atoms of the acetamido group are essentially planar, with a maximum deviation of 0.0085 (12) Å. In comparison with related structures, the carbonyl C=O bond is slightly elongated [1.249 (2) Å], whereas the amide C-N bond is shortened [1.292 (2) Å].

Online 20 May 2009


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