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Acta Cryst. (2009). E65, o1255  [ doi:10.1107/S1600536809016730 ]

N,N'-Bis[(E)-(6-methyl-2-pyridyl)methylene]hexane-1,6-diamine

M. Ramos Silva, J. A. Silva, A. Matos Beja and A. J. F. N. Sobral

Abstract: The title compound, C20H26N4, is composed of two (6-methyl-2-pyridyl)methylene units linked by a 1,6-diamine hexane chain. The molecule has Ci symmetry with the inversion center situated at the mid-point of the central C-C bond. The alkyl chain has an all-trans conformation, with all the non-H atoms sharing the same plane [maximum deviation 0.004 (3) Å]. The pyridylmethylene groups are also planar [maximum deviation 0.009 (3) Å], making an angle of 53.78 (19)° with the hexane chain plane. In the crystal, the molecules assemble in layers, stacking along the a axis. The stacks are hold together by attractive interactions between [pi] electron systems.

Online 14 May 2009


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