Acta Cryst. (2009). E65, m666  [ doi:10.1107/S1600536809017978 ]

Aquabis(2-amino-1,3-thiazole-4-acetato-²O,N³)nickel(II)

Q.-F. He, D.-S. Li, J. Zhao, X.-J. Ke and C. Li

Abstract: In the crystal structure of the title compound, [Ni(C₅H₅N₂O₂S)₂(H₂O)], the Ni^II cation is located on a twofold rotation axis and chelated by two 2-amino-1,3-thiazole-4-acetate (ata) anions in the basal coordination plane; a water molecule located on the same twofold rotation axis completes the distorted square-pyramidal coordination geometry. Intermolecular O-HO and N-HO hydrogen bonding, as well as - stacking between parallel thiazole rings [centroid-centroid distance 3.531 (8) Å], helps to stabilize the crystal structure.

Online 20 May 2009

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