Acta Cryst. (2009). E65, m783  [ doi:10.1107/S1600536809021783 ]

Diaquabis(ciprofloxacinato)manganese(II) 2,2'-bipyridine solvate tetrahydrate

Y.-J. Wang, N. Wang, R.-D. Hu, Q.-Y. Lin and Y.-Y. Wang

Abstract: In the crystal structure of the title compound {systematic name: diaquabis[1-cyclopropyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato]manganese(II) 2,2'-bipyridine solvate tetrahydrate}, [Mn(C₁₇H₁₇FN₃O₃)₂(H₂O)₂]·C₁₀H₈N₂·4H₂O, the pyridone O and one carboxylate O atom of the two ciprofloxacin ligands are bound to the Mn^II ion and occupy the equatorial positions, while the two aqua O atoms lie in the apical positions resulting in a distorted octahedral geometry. The crystal packing is stabilized by N-HO and O-HO hydrogen bonding interactions.

Online 17 June 2009

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