Acta Cryst. (2009). E65, m793  [ doi:10.1107/S1600536809022405 ]

{Bis[2-(diphenylphosphino)ethyl]phenylphosphine-³P,P',P''}chloridoplatinium(II) hexafluoridophosphate

S. A. Heston, B. C. Noll and M. L. Helm

Abstract: In the title compound, [PtCl(C₃₄H₃₃P₃)]PF₆, the Pt^II cation adopts a distorted square-planar PtClP₃ geometry, arising from the P,P',P''-tridentate triphos ligand and a chloride ion. Four of the F atoms of the PF₆^- anion are disordered over two sets of positions in a 0.614 (17):0.386 (17) ratio.

Online 20 June 2009

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