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Acta Cryst. (2009). E65, m793    [ doi:10.1107/S1600536809022405 ]

{Bis[2-(diphenylphosphino)ethyl]phenylphosphine-[kappa]3P,P',P''}chloridoplatinium(II) hexafluoridophosphate

S. A. Heston, B. C. Noll and M. L. Helm

Abstract top

In the title compound, [PtCl(C34H33P3)]PF6, the PtII cation adopts a distorted square-planar PtClP3 geometry, arising from the P,P',P''-tridentate triphos ligand and a chloride ion. Four of the F atoms of the PF6- anion are disordered over two sets of positions in a 0.614 (17):0.386 (17) ratio.

Comment top

The crystal structure of the title compound, (I), consists of a [Pt(triphos)Cl]+ cation and disordered PF6- anion (Fig. 1). The cation shows a distorted square planar geometry (Table 1) around the metal center with a non-coordinating PF6- anion.

Related literature top

The corresponding complex with a Pd(II) metal center is concurently published (Vorce et al., 2009). The corresponding PtII complex has been previously reported as a CuCl2- salt (Fernadez et al., 2005). The corresponding complexes with both PtII and Pd(II) have been previously reported as chloride and diphenyltetrachlorostannate(IV) salts (Sevillano et al., 1999a; Garcia-Seijo et al., 2001; Housecroft et al., 1990). For other group 10–triphos complexes, see: Sevillano et al. (1999b); Muller et al. (2000); Aizawa et al. (2002); Bertinsson et al. (1983); Autissier et al. (2005). For related literature. see: Fernandez et al. (2005); King et al. (1971).

Experimental top

The synthesis of (I) by a previously reported proceedure (King, et al., 1971). Crystals where grown by slow solvent evaporation of a saturated dichloromethane solution of (I).

Computing details top

Data collection: APEX2 (Bruker, 2008); cell refinement: SAINT (Bruker, 2008); data reduction: SAINT and XPREP (Bruker, 2008); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008b); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008b); molecular graphics: SHELXTL (Sheldrick, 2008b); software used to prepare material for publication: SHELXL97 (Sheldrick, 2008b).

Figures top
[Figure 1] Fig. 1. The molecular structure of (I), with 50% probability displacement ellipsoids.
[Figure 2] Fig. 2. The molecular structure of (I), with atom labels and 50% probability displacement ellipsoids. Hydrogen atoms are omitted for clarity.
{Bis[2-(diphenylphosphino)ethyl]phenylphosphine- κ3P,P',P''}chloridoplatinium(II) hexafluoridophosphate top
Crystal data top
[PtCl(C34H33P3)]PF6F(000) = 1784
Mr = 910.02Dx = 1.725 Mg m−3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybcCell parameters from 9957 reflections
a = 11.3870 (11) Åθ = 2.5–25.1°
b = 19.6221 (18) ŵ = 4.32 mm−1
c = 16.4439 (16) ÅT = 298 K
β = 107.528 (3)°Plate, colorless
V = 3503.6 (6) Å30.50 × 0.30 × 0.10 mm
Z = 4
Data collection top
Bruker SMART X2S
diffractometer		6155 independent reflections
Radiation source: microfocus sealed tube, Bruker5269 reflections with I > 2σ(I)
graphiteRint = 0.025
Detector resolution: 8.33 pixels mm-1θmax = 25.1°, θmin = 2.8°
ω scansh = −13→13
Absorption correction: multi-scan
(SADABS; Sheldrick, 2008a)		k = −18→23
Tmin = 0.21, Tmax = 0.65l = −19→19
21968 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.020Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.049H-atom parameters constrained
S = 1.03 w = 1/[σ2(Fo2) + (0.0227P)2 + 1.641P]
where P = (Fo2 + 2Fc2)/3
6155 reflections(Δ/σ)max = 0.002
452 parametersΔρmax = 0.58 e Å−3
204 restraintsΔρmin = −0.41 e Å−3
Crystal data top
[PtCl(C34H33P3)]PF6V = 3503.6 (6) Å3
Mr = 910.02Z = 4
Monoclinic, P21/cMo Kα radiation
a = 11.3870 (11) ŵ = 4.32 mm−1
b = 19.6221 (18) ÅT = 298 K
c = 16.4439 (16) Å0.50 × 0.30 × 0.10 mm
β = 107.528 (3)°
Data collection top
Bruker SMART X2S
diffractometer		6155 independent reflections
Absorption correction: multi-scan
(SADABS; Sheldrick, 2008a)		5269 reflections with I > 2σ(I)
Tmin = 0.21, Tmax = 0.65Rint = 0.025
21968 measured reflectionsθmax = 25.1°
Refinement top
R[F2 > 2σ(F2)] = 0.020H-atom parameters constrained
wR(F2) = 0.049Δρmax = 0.58 e Å−3
S = 1.03Δρmin = −0.41 e Å−3
6155 reflectionsAbsolute structure: ?
452 parametersFlack parameter: ?
204 restraintsRogers parameter: ?
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. The PF6 anion is disordered, showing alternate positions of the 4 F atoms F3—F6 when rotated about the axis F1—P4—F2. A second orientation for these equatorial positions was located. Based on the thermal parameters, additional positions are indicated, but were not modeled. To improve the quality of the fit for this anion, distance restraints (SHELX SADI) were added for the P–F bonds, as well as for the F–F interatomic distances. These account for 156 of the 204 restraints applied. The remaining restraints (ISOR) were applied to the anisotropic displacement parameters for the fluorine atoms.

Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Pt10.139852 (10)0.364806 (6)0.374003 (7)0.03173 (5)
Cl10.31867 (8)0.35123 (5)0.48942 (5)0.0498 (2)
P10.22200 (7)0.43573 (4)0.29227 (5)0.03695 (19)
P2−0.03648 (7)0.37743 (4)0.27189 (5)0.03518 (19)
P30.03774 (7)0.28264 (4)0.42630 (5)0.03706 (19)
C10.3286 (3)0.39017 (18)0.2487 (2)0.0417 (8)
C20.3950 (4)0.3357 (2)0.2925 (3)0.0696 (12)
H20.38510.32270.34440.084*
C30.4758 (5)0.3003 (3)0.2602 (4)0.0929 (17)
H30.52090.26410.29090.111*
C40.4896 (4)0.3182 (3)0.1838 (3)0.0811 (14)
H40.54220.29330.16140.097*
C50.4268 (4)0.3724 (3)0.1397 (3)0.0809 (15)
H50.43820.38500.08810.097*
C60.3458 (4)0.4088 (2)0.1716 (2)0.0662 (12)
H60.30300.44570.14130.079*
C70.2923 (3)0.51580 (17)0.3367 (2)0.0448 (8)
C80.3091 (4)0.5681 (2)0.2843 (3)0.0690 (12)
H80.28890.56160.22570.083*
C90.3563 (5)0.6303 (2)0.3202 (4)0.0815 (15)
H90.36730.66530.28520.098*
C100.3863 (4)0.6405 (2)0.4054 (4)0.0774 (15)
H100.41620.68270.42830.093*
C110.3726 (4)0.5886 (2)0.4579 (3)0.0774 (14)
H110.39500.59540.51660.093*
C120.3255 (3)0.5262 (2)0.4237 (3)0.0587 (10)
H120.31620.49130.45950.070*
C130.0924 (3)0.46082 (19)0.2000 (2)0.0480 (9)
H13A0.05340.50120.21410.058*
H13B0.12260.47180.15240.058*
C14−0.0024 (3)0.40301 (19)0.1745 (2)0.0459 (8)
H14A0.03110.36490.15100.055*
H14B−0.07660.41880.13200.055*
C15−0.1372 (3)0.44123 (17)0.2947 (2)0.0392 (8)
C16−0.2526 (3)0.4525 (2)0.2376 (2)0.0612 (11)
H16−0.27690.42920.18600.073*
C17−0.3320 (4)0.4987 (2)0.2575 (3)0.0777 (13)
H17−0.40970.50610.21920.093*
C18−0.2964 (4)0.5334 (2)0.3334 (3)0.0718 (12)
H18−0.35010.56420.34620.086*
C19−0.1830 (4)0.5230 (2)0.3901 (3)0.0655 (11)
H19−0.15930.54680.44130.079*
C20−0.1031 (3)0.47681 (18)0.3711 (2)0.0512 (9)
H20−0.02580.46960.41000.061*
C21−0.1212 (3)0.29792 (17)0.2618 (2)0.0446 (8)
H21A−0.20520.30410.22550.054*
H21B−0.08240.26310.23680.054*
C22−0.1201 (3)0.27699 (19)0.3519 (2)0.0500 (9)
H22A−0.15020.23070.35100.060*
H22B−0.17430.30670.37130.060*
C230.0305 (3)0.29942 (17)0.5330 (2)0.0413 (8)
C24−0.0603 (3)0.3399 (2)0.5480 (2)0.0529 (9)
H24−0.12740.35330.50270.063*
C25−0.0518 (4)0.3605 (2)0.6305 (3)0.0605 (11)
H25−0.11350.38740.64020.073*
C260.0467 (4)0.3415 (2)0.6974 (2)0.0590 (10)
H260.05330.35640.75230.071*
C270.1362 (4)0.3003 (2)0.6833 (2)0.0614 (11)
H270.20240.28650.72900.074*
C280.1287 (3)0.2791 (2)0.6017 (2)0.0538 (9)
H280.18960.25120.59290.065*
C290.1039 (3)0.19806 (16)0.42953 (19)0.0387 (8)
C300.0425 (4)0.14216 (19)0.4497 (2)0.0539 (10)
H30−0.03220.14830.46090.065*
C310.0923 (5)0.0778 (2)0.4532 (3)0.0677 (12)
H310.05150.04070.46730.081*
C320.2015 (4)0.0680 (2)0.4359 (3)0.0675 (12)
H320.23430.02440.43810.081*
C330.2626 (4)0.1225 (2)0.4153 (3)0.0610 (11)
H330.33620.11570.40290.073*
C340.2149 (3)0.18766 (18)0.4131 (2)0.0456 (8)
H340.25750.22460.40050.055*
P40.33951 (10)0.86107 (6)0.53542 (7)0.0655 (3)
F10.2344 (3)0.91309 (17)0.5407 (2)0.1331 (13)
F20.4424 (3)0.81198 (16)0.5283 (2)0.1263 (12)
F30.4311 (7)0.8949 (6)0.6137 (6)0.170 (6)0.614 (17)
F40.2458 (8)0.8302 (5)0.4551 (7)0.181 (7)0.614 (17)
F50.3788 (11)0.9131 (4)0.4771 (7)0.143 (6)0.614 (17)
F60.2992 (7)0.8122 (5)0.5916 (7)0.196 (7)0.614 (17)
F3'0.3623 (16)0.8459 (7)0.6302 (5)0.170 (11)0.386 (17)
F4'0.3028 (14)0.8713 (10)0.4399 (5)0.184 (10)0.386 (17)
F5'0.4294 (9)0.9199 (4)0.5545 (15)0.153 (11)0.386 (17)
F6'0.2434 (11)0.8018 (5)0.5150 (11)0.141 (9)0.386 (17)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Pt10.02685 (7)0.03558 (8)0.03213 (7)−0.00116 (5)0.00792 (5)0.00172 (5)
Cl10.0352 (4)0.0585 (6)0.0467 (5)−0.0016 (4)−0.0013 (4)0.0038 (4)
P10.0324 (4)0.0385 (5)0.0422 (5)0.0009 (4)0.0147 (4)0.0056 (4)
P20.0290 (4)0.0438 (5)0.0311 (4)0.0000 (4)0.0066 (3)−0.0002 (3)
P30.0322 (4)0.0416 (5)0.0385 (4)−0.0023 (4)0.0124 (4)0.0045 (4)
C10.0343 (17)0.046 (2)0.0465 (19)−0.0013 (15)0.0144 (15)−0.0008 (16)
C20.069 (3)0.069 (3)0.086 (3)0.022 (2)0.047 (3)0.023 (2)
C30.095 (4)0.080 (4)0.126 (4)0.042 (3)0.067 (4)0.029 (3)
C40.069 (3)0.085 (4)0.103 (4)0.011 (3)0.046 (3)−0.021 (3)
C50.061 (3)0.134 (5)0.056 (3)0.015 (3)0.029 (2)−0.004 (3)
C60.057 (2)0.095 (3)0.051 (2)0.021 (2)0.023 (2)0.009 (2)
C70.0338 (18)0.039 (2)0.064 (2)−0.0003 (15)0.0188 (17)0.0049 (17)
C80.081 (3)0.051 (3)0.087 (3)−0.012 (2)0.043 (3)0.004 (2)
C90.083 (3)0.046 (3)0.122 (5)−0.012 (2)0.041 (3)0.014 (3)
C100.047 (2)0.049 (3)0.122 (4)−0.014 (2)0.003 (3)−0.006 (3)
C110.063 (3)0.063 (3)0.084 (3)−0.006 (2)−0.014 (2)−0.005 (3)
C120.049 (2)0.048 (2)0.068 (3)−0.0065 (18)0.0007 (19)0.0046 (19)
C130.0418 (19)0.057 (2)0.048 (2)0.0080 (17)0.0177 (16)0.0167 (17)
C140.0408 (18)0.063 (2)0.0335 (17)0.0071 (18)0.0111 (14)0.0050 (16)
C150.0340 (17)0.042 (2)0.0423 (18)0.0025 (15)0.0124 (15)0.0026 (15)
C160.044 (2)0.074 (3)0.058 (2)0.008 (2)0.0042 (18)−0.010 (2)
C170.045 (2)0.084 (3)0.094 (3)0.020 (2)0.006 (2)−0.006 (3)
C180.057 (3)0.064 (3)0.098 (3)0.015 (2)0.028 (3)−0.015 (3)
C190.066 (3)0.063 (3)0.067 (3)0.008 (2)0.019 (2)−0.017 (2)
C200.045 (2)0.052 (2)0.053 (2)0.0059 (17)0.0090 (17)−0.0046 (18)
C210.0377 (18)0.044 (2)0.0468 (19)−0.0053 (15)0.0043 (15)−0.0068 (16)
C220.0346 (18)0.055 (2)0.058 (2)−0.0089 (16)0.0104 (16)0.0066 (18)
C230.0398 (18)0.045 (2)0.0432 (18)−0.0014 (15)0.0189 (15)0.0061 (15)
C240.047 (2)0.063 (2)0.051 (2)0.0083 (19)0.0199 (18)0.0037 (19)
C250.060 (3)0.069 (3)0.062 (3)0.009 (2)0.032 (2)0.000 (2)
C260.076 (3)0.062 (3)0.046 (2)0.002 (2)0.027 (2)0.0018 (19)
C270.067 (3)0.073 (3)0.042 (2)0.012 (2)0.0129 (19)0.0082 (19)
C280.055 (2)0.062 (3)0.046 (2)0.0145 (19)0.0190 (18)0.0076 (18)
C290.0413 (18)0.040 (2)0.0339 (16)−0.0049 (15)0.0096 (14)0.0008 (14)
C300.060 (2)0.053 (3)0.051 (2)−0.0172 (19)0.0205 (19)−0.0012 (18)
C310.096 (4)0.043 (3)0.061 (3)−0.020 (2)0.020 (2)0.0018 (19)
C320.086 (3)0.042 (2)0.063 (3)0.008 (2)0.005 (2)−0.007 (2)
C330.057 (2)0.053 (3)0.069 (3)0.007 (2)0.012 (2)−0.007 (2)
C340.045 (2)0.043 (2)0.049 (2)−0.0006 (16)0.0130 (16)0.0008 (16)
P40.0518 (6)0.0859 (9)0.0608 (7)0.0022 (6)0.0199 (5)0.0198 (6)
F10.085 (2)0.135 (3)0.193 (4)0.031 (2)0.062 (2)0.027 (3)
F20.100 (2)0.108 (3)0.178 (3)0.0275 (19)0.052 (2)−0.005 (2)
F30.082 (5)0.309 (16)0.115 (7)−0.058 (7)0.025 (4)−0.069 (8)
F40.133 (9)0.174 (11)0.166 (11)0.000 (7)−0.061 (7)−0.044 (8)
F50.200 (12)0.121 (8)0.155 (10)0.039 (7)0.122 (9)0.062 (7)
F60.121 (6)0.265 (13)0.210 (13)−0.036 (7)0.061 (8)0.170 (11)
F3'0.27 (3)0.174 (15)0.051 (5)0.124 (16)0.023 (9)0.000 (7)
F4'0.183 (16)0.31 (3)0.047 (6)−0.042 (14)0.010 (8)0.053 (10)
F5'0.083 (8)0.077 (7)0.31 (3)−0.036 (5)0.079 (15)−0.040 (13)
F6'0.163 (15)0.110 (10)0.198 (19)−0.074 (10)0.130 (15)−0.031 (10)
Geometric parameters (Å, °) top
Pt1—P22.2095 (8)C17—C181.371 (6)
Pt1—P32.3007 (8)C17—H170.9300
Pt1—P12.3185 (8)C18—C191.361 (6)
Pt1—Cl12.3434 (8)C18—H180.9300
P1—C71.814 (4)C19—C201.384 (5)
P1—C11.819 (3)C19—H190.9300
P1—C131.836 (3)C20—H200.9300
P2—C151.812 (3)C21—C221.535 (5)
P2—C211.815 (3)C21—H21A0.9700
P2—C141.828 (3)C21—H21B0.9700
P3—C231.812 (3)C22—H22A0.9700
P3—C291.817 (3)C22—H22B0.9700
P3—C221.848 (3)C23—C241.383 (5)
C1—C21.380 (5)C23—C281.387 (5)
C1—C61.389 (5)C24—C251.392 (5)
C2—C31.381 (6)C24—H240.9300
C2—H20.9300C25—C261.365 (6)
C3—C41.359 (6)C25—H250.9300
C3—H30.9300C26—C271.375 (5)
C4—C51.362 (6)C26—H260.9300
C4—H40.9300C27—C281.382 (5)
C5—C61.388 (6)C27—H270.9300
C5—H50.9300C28—H280.9300
C6—H60.9300C29—C341.385 (4)
C7—C121.381 (5)C29—C301.393 (5)
C7—C81.390 (5)C30—C311.379 (5)
C8—C91.390 (6)C30—H300.9300
C8—H80.9300C31—C321.370 (6)
C9—C101.352 (7)C31—H310.9300
C9—H90.9300C32—C331.372 (6)
C10—C111.375 (6)C32—H320.9300
C10—H100.9300C33—C341.385 (5)
C11—C121.386 (5)C33—H330.9300
C11—H110.9300C34—H340.9300
C12—H120.9300P4—F61.496 (5)
C13—C141.535 (5)P4—F5'1.512 (8)
C13—H13A0.9700P4—F4'1.512 (8)
C13—H13B0.9700P4—F3'1.530 (8)
C14—H14A0.9700P4—F31.542 (7)
C14—H14B0.9700P4—F21.548 (3)
C15—C161.383 (5)P4—F41.549 (6)
C15—C201.387 (5)P4—F51.556 (6)
C16—C171.387 (5)P4—F6'1.563 (8)
C16—H160.9300P4—F11.595 (3)
P2—Pt1—P385.22 (3)C18—C19—C20119.7 (4)
P2—Pt1—P185.71 (3)C18—C19—H19120.1
P3—Pt1—P1167.13 (3)C20—C19—H19120.1
P2—Pt1—Cl1175.83 (3)C19—C20—C15120.7 (3)
P3—Pt1—Cl191.79 (3)C19—C20—H20119.7
P1—Pt1—Cl197.69 (3)C15—C20—H20119.7
C7—P1—C1108.56 (15)C22—C21—P2107.0 (2)
C7—P1—C13104.36 (16)C22—C21—H21A110.3
C1—P1—C13105.78 (16)P2—C21—H21A110.3
C7—P1—Pt1119.51 (12)C22—C21—H21B110.3
C1—P1—Pt1111.53 (12)P2—C21—H21B110.3
C13—P1—Pt1105.99 (11)H21A—C21—H21B108.6
C15—P2—C21105.12 (16)C21—C22—P3110.3 (2)
C15—P2—C14107.82 (16)C21—C22—H22A109.6
C21—P2—C14113.75 (16)P3—C22—H22A109.6
C15—P2—Pt1114.03 (11)C21—C22—H22B109.6
C21—P2—Pt1108.04 (11)P3—C22—H22B109.6
C14—P2—Pt1108.22 (11)H22A—C22—H22B108.1
C23—P3—C29106.08 (15)C24—C23—C28118.9 (3)
C23—P3—C22109.46 (16)C24—C23—P3122.1 (3)
C29—P3—C22106.05 (16)C28—C23—P3118.4 (3)
C23—P3—Pt1114.22 (11)C23—C24—C25120.3 (4)
C29—P3—Pt1113.54 (11)C23—C24—H24119.9
C22—P3—Pt1107.16 (11)C25—C24—H24119.9
C2—C1—C6118.3 (3)C26—C25—C24120.4 (4)
C2—C1—P1120.0 (3)C26—C25—H25119.8
C6—C1—P1121.6 (3)C24—C25—H25119.8
C1—C2—C3120.9 (4)C25—C26—C27119.7 (4)
C1—C2—H2119.6C25—C26—H26120.1
C3—C2—H2119.6C27—C26—H26120.1
C4—C3—C2120.1 (4)C26—C27—C28120.6 (4)
C4—C3—H3120.0C26—C27—H27119.7
C2—C3—H3120.0C28—C27—H27119.7
C3—C4—C5120.4 (4)C27—C28—C23120.2 (3)
C3—C4—H4119.8C27—C28—H28119.9
C5—C4—H4119.8C23—C28—H28119.9
C4—C5—C6120.2 (4)C34—C29—C30118.9 (3)
C4—C5—H5119.9C34—C29—P3121.6 (3)
C6—C5—H5119.9C30—C29—P3119.5 (3)
C5—C6—C1120.1 (4)C31—C30—C29120.1 (4)
C5—C6—H6119.9C31—C30—H30120.0
C1—C6—H6119.9C29—C30—H30120.0
C12—C7—C8119.1 (4)C32—C31—C30120.5 (4)
C12—C7—P1119.7 (3)C32—C31—H31119.8
C8—C7—P1121.1 (3)C30—C31—H31119.8
C7—C8—C9119.5 (4)C31—C32—C33120.1 (4)
C7—C8—H8120.3C31—C32—H32119.9
C9—C8—H8120.3C33—C32—H32119.9
C10—C9—C8121.0 (4)C32—C33—C34120.1 (4)
C10—C9—H9119.5C32—C33—H33119.9
C8—C9—H9119.5C34—C33—H33119.9
C9—C10—C11119.9 (4)C29—C34—C33120.3 (3)
C9—C10—H10120.0C29—C34—H34119.9
C11—C10—H10120.0C33—C34—H34119.9
C10—C11—C12120.2 (5)F5'—P4—F4'94.2 (8)
C10—C11—H11119.9F5'—P4—F3'92.3 (7)
C12—C11—H11119.9F4'—P4—F3'173.1 (8)
C7—C12—C11120.2 (4)F6—P4—F390.9 (5)
C7—C12—H12119.9F6—P4—F291.6 (4)
C11—C12—H12119.9F5'—P4—F290.6 (4)
C14—C13—P1110.6 (2)F4'—P4—F289.0 (5)
C14—C13—H13A109.5F3'—P4—F293.2 (4)
P1—C13—H13A109.5F3—P4—F289.6 (4)
C14—C13—H13B109.5F6—P4—F490.9 (5)
P1—C13—H13B109.5F3—P4—F4177.5 (5)
H13A—C13—H13B108.1F2—P4—F492.0 (3)
C13—C14—P2106.3 (2)F6—P4—F5178.6 (5)
C13—C14—H14A110.5F3—P4—F589.1 (4)
P2—C14—H14A110.5F2—P4—F589.8 (3)
C13—C14—H14B110.5F4—P4—F589.0 (5)
P2—C14—H14B110.5F5'—P4—F6'178.3 (6)
H14A—C14—H14B108.7F4'—P4—F6'85.3 (8)
C16—C15—C20118.9 (3)F3'—P4—F6'88.1 (6)
C16—C15—P2120.1 (3)F2—P4—F6'91.0 (4)
C20—C15—P2120.9 (3)F6—P4—F190.1 (4)
C15—C16—C17119.9 (4)F5'—P4—F188.4 (4)
C15—C16—H16120.1F4'—P4—F189.7 (5)
C17—C16—H16120.1F3'—P4—F188.2 (4)
C18—C17—C16120.2 (4)F3—P4—F190.5 (4)
C18—C17—H17119.9F2—P4—F1178.3 (2)
C16—C17—H17119.9F4—P4—F187.8 (3)
C19—C18—C17120.6 (4)F5—P4—F188.5 (3)
C19—C18—H18119.7F6'—P4—F190.0 (4)
C17—C18—H18119.7
Table 1
Selected geometric parameters (Å) top
Pt1—P22.2095 (8)Pt1—P12.3185 (8)
Pt1—P32.3007 (8)Pt1—Cl12.3434 (8)
Acknowledgements top

We thank Research Corporation Cottrell Science Award (No. 7293) for funding that supported this research.

references
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