Acta Cryst. (2009). E65, o1494  [ doi:10.1107/S1600536809020698 ]

(Methyldiphenylphosphoranylidene)ammonium chloride

C. Valerio-Cárdenas, L. Ortiz-Frade and J.-M. Grévy M.

Abstract: The title compound, C₁₃H₁₅NP⁺·Cl^-, was obtained by hydrolysis of the N-trimethysilyl derivative of methydiphenyliminophosphine. The dihedral angle between the phenyl rings in the cation is 61.5 (3)°. In the crystal structure, intermolecular N-HCl hydrogen bonds links the two components, forming a centrosymmetric 2 + 2 aggregate.

Online 6 June 2009

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