Acta Cryst. (2009). E65, m795-m796  [ doi:10.1107/S1600536809022661 ]

(N⁴-n-Butylpyridine-4-carbothioamide-N⁴)chloridobis(dimethylglyoximato-²N,N')cobalt(III) hemihydrate

C. Revathi, A. Dayalan and K. SethuSankar

Abstract: The title compound, trans-[Co(C₄H₇N₂O₂)₂Cl(C₁₀H₁₄N₂S)]·0.5H₂O, contains two independent molecules in the asymmetric unit in which the Co^III ions are coordinated in slightly distorted octahedral coordination environments. The bis-chelating glyoximate ligands, which occupy equatorial sites, are linked by interligand O-HO hydrogen bonds. The dihedral angles between the mean planes of the glyoximate ligands in each molecule are 2.07 (8) and 1.60 (1)°. The asymmetric unit contains a solvent water molecule which is disordered over two sites with refined occupancies 0.64 (2) and 0.36 (2).

Online 20 June 2009

Copyright © International Union of Crystallography
IUCr Webmaster