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Acta Cryst. (2009). E65, i55  [ doi:10.1107/S1600536809021734 ]

Ni2Si(P2O7)2

Y. Toubi, R. Essehli, M. Dusek, K. Fejfarová and B. El Bali

Abstract: Dinickel(II) silicon bis[diphosphate(4-)], Ni2Si(P2O7)2, is isotypic with other phosphates of the formula M2Si(P2O7)2 (M = Co, Cd). All atoms except Si (site symmetry 2) are found in general positions. Ni2O10 dimers formed from edge-sharing NiO6 octahedra are linked by corners and O-P-O bridges, forming slabs parallel to (100), which are in turn interconnected by O-Si-O contacts.

Online 27 June 2009


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