Acta Cryst. (2009). E65, m828  [ doi:10.1107/S1600536809023423 ]

Dichlorido[tris(1H-benzimidazol-2-ylmethyl)amine-⁴N,N³,N^3',N^3'']iron(III) chloride tetrahydrofuran monosolvate monohydrate

D. Wang

Abstract: In the title compound, [FeCl₂(C₂₄H₂₁N₇)]Cl·C₄H₈O·H₂O, the Fe^III atom is coordinated by four N atoms of the polybenzimidazole ligand and two Cl atoms in a distorted octahedral environment. The cation, anion, the uncoordinated water molecule and the THF solvent molecule are linked by hydrogen bonds into a three-dimensional network structure. The THF molecule is disordered with two sets of sites in a 0.58 (1):0.42 (2) ratio..

Online 27 June 2009

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