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Acta Cryst. (2009). E65, m732  [ doi:10.1107/S1600536809020479 ]

Poly[diaqua([mu]4-3,5-dicarboxylatopyrazol-1-ido-[kappa]6N1,O5:N2,O3:O3':O5,O5')lanthanum(III)]

J. Xia and J.-F. Wei

Abstract: In the title coordination polymer, [La(C5HN2O4)(H2O)2]n, the lanthanum(III) metal centre is nine-coordinated, with a distorted tricapped trigonal prismatic geometry, by the O atoms of two water molecules and by two N and five O atoms of two N,O-bidentate, one O,O'-bidentate and one O-monodentate 3,5-dicarboxylatopyrazol-1-ide ligands. The polymeric three-dimensional structure is stabilized by intermolecular O-H...O hydrogen bonds.

Online 6 June 2009


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