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Acta Cryst. (2009). E65, m708  [ doi:10.1107/S1600536809020352 ]

Dibromidobis(1,10-phenanthroline-[kappa]2N,N')cadmium(II)

Y.-H. Sun, S.-F. Luo, X.-Z. Zhang and Z.-Y. Du

Abstract: The title compound, [CdBr2(C12H8N2)2], synthesized by the hydrothermal reaction of Cd(CH3COO)2·2H2O with NaBr and 1,10-phenanthroline, has the CdII cation coordinated by two Br- anions and four N atoms from two 1,10-phenanthroline ligands in a distorted octahedral geometry. The crystal packing is stabilized by intermolecular [pi]-[pi] interactions with centroid-centroid distances 3.572 (1) and 3.671 (1) Å together with C-H...Br hydrogen bonds.

Online 6 June 2009


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