![[HTML version]](/e/graphics/htmlborder.gif)
![[PDF version]](/e/graphics/pdfborder.gif)
![[CIF]](/e/graphics/cifborder.gif)
![[3d view]](/e/graphics/3dviewborder.gif)
![[Structure Factors]](/e/graphics/structurefactorsborder.gif)
![[Supplementary Material]](/e/graphics/supplementarymaterialsborder.gif)
![[CIF check Report]](/e/graphics/checkcifborder.gif)
![[Issue contents]](/e/graphics/issuecontentsborder.gif)
![[Open access]](/e/graphics/free.gif)
![[Contents scheme]](zl2221contents.gif)
Acta Cryst. (2009). E65, m814 [ doi:10.1107/S1600536809023356 ]
![[kappa]](/logos/entities/kappa_rmgif.gif)
3N1,N1',N1'']copper(II)} [cuprate(I)-di-![[mu]](/logos/entities/mu_rmgif.gif)
2-thiocyanato-2N:S;2S:N]]Abstract: The title compound, {[Cu(C20H14N4)2][Cu2(NCS)4]}n, was obtained by reacting copper acetate hydrate, ammonium thiocyanate and 4'-(3-pyridyl)-2,2':6',2''-terpyridine (3-pytpy) under solvothermal conditions. The polymeric complex is isostructural with the 4'-phenyl-2,2':6',2''-terpyridine (phtpy) analogue. All intramolecular distances and angles are very similar for the two structures. Substitution of a phenyl group with a pyridyl group has no significant effect on the crystal packing which is accomplished by C-H
N and C-HS hydrogen-bonding interactions.
Online 24 June 2009
Copyright © International Union of Crystallography
IUCr Webmaster