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Acta Cryst. (2009). E65, o2099-o2100  [ doi:10.1107/S1600536809030761 ]

1-Ethyl-2-tosyl-4,4,6-trimethyl-2,3,3a,4-tetrahydro-1H-pyrrolo[3,4-c]pyrano[6,5-b]quinoline-11(6H)-one monohydrate

K. Chinnakali, D. Sudha, M. Jayagobi, R. Raghunathan and H.-K. Fun

Abstract: In the title compound, C26H30N2O4S·H2O, the pyrrolidine and dihydropyran rings adopt envelope conformations and they are cis-fused. The sulfonyl group has a distorted tetrahedral geometry. In the crystal structure, the molecules are linked into a ribbon-like structure along the a axis by O/C-H...O hydrogen bonds involving water molecules and C-H...[pi] interactions involving the sulfonyl-bound phenyl ring. Adjacent ribbons are cross-linked via C-H...O hydrogen bonds involving a sulfonyl O atom and C-H...[pi] interactions involving the pyridinone ring.

Online 8 August 2009


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