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Volume 65 
Part 9 
Page m1116  
September 2009  

Received 25 July 2009
Accepted 17 August 2009
Online 22 August 2009

[bx2229sup1]
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Key indicators
Single-crystal X-ray study
T = 273 K
Mean [sigma](C-C) = 0.004 Å
Disorder in main residue
R = 0.033
wR = 0.091
Data-to-parameter ratio = 13.4
Details
Open access

catena-Poly[[bis(p-toluenesulfonato-[kappa]O)palladium(II)]bis([mu]-1,3-di-4-pyridylpropane-[kappa]2N:N')]

Suwen Wang,a Tianyu Yang,b Zhongfang Lia* and Xianjin Yua

aCollege of Chemical Engineering, Shandong University of Technology, Zibo 255049, People's Republic of China, and bThe College of Life Sciences, Northwest University, Xi-an 710069, People's Republic of China
Correspondence e-mail: zhfli_sdut@yahoo.cn

In the title compound, [Pd(C7H7O3S)2(C13H14N2)2]n, the metal ion, located on a twofold rotation axis, exhibits a slightly distorted octahedral coordination environment, with bond angles that deviate by at most 2.2° from an ideal geometry, completed by two O atoms from two deprotonated p-toluenesulfonic acid ligands and four N atoms from four 1,3-di-4-pyridylpropane ligands. One of the sulfonate O atoms is disordered over two positions [ratio 0.70 (5):0.30 (5)].

Related literature

For the potential applications of metal-organic frameworks, see: Jia et al. (2007[Jia, H. P., Li, W., Ju, Z. F. & Zhang, J. (2007). Inorg. Chem. Commun. 10, 265-268.]); Li et al. (1996[Li, H., Eddaoudi, M. O., Keffe, M. & Yaghi, O. M. (1996). Nature (London), 402, 276-279.]); Seo et al. (2000[Seo, J. S., Whang, D., Lee, H., Jun, S. I., Oh, J., Jeon, Y. J. & Kim, K. (2000). Nature (London), 404, 982-986.]); Hagrman et al. (1999[Hagrman, P. J., Hagrman, D. & Zubieta, J. (1999). Angew. Chem. Int. Ed. 38, 2638-2684.]); Yaghi et al. (1998[Yaghi, O. M., Li, H., Davis, C., Richardson, D. & Groy, T. L. (1998). Acc. Chem. Res. 31, 474-484.]); Kortz et al. (2003[Kortz, U., Hamzeh, S. S. & Nasser, N. A. (2003). Chem. Eur. J. 9, 2945-2952.]); Liu et al. (2007[Liu, B., Li, X. M., Li, C. B., Gao, G. G. & Che, G. B. (2007). Chin. J. Struct. Chem. 26, 679-682.]); Wang et al. (2007[Wang, Y. T., Tang, G. M., Wu, Y., Qin, X. Y. & Qin, D. W. (2007). J. Mol. Struct. 831, 61-68.]). 1,3-Di(4-pyridyl)propane has versatile coordination modes with transition metal centers, see: Xu et al. (2004[Xu, C., Mao, H. Y., Zhang, H. Y., Liu, H. L., Wu, Q. A., Hou, H. W. & Zhu, Y. (2004). Chin. J. Struct. Chem. 23, 567-570.]); Zhu et al. (2002[Zhu, L. G., Cai, G. Q., Susumu, K. & Ho-Chol, C. (2002). Chin. J. Inorg. Chem. 18, 911-914.]); Mock & Morsch (2001[Mock, W. L. & Morsch, L. A. (2001). Tetrahedron, 57, 2957-2964.]).

[Scheme 1]

Experimental

Crystal data

  • [Pd(C7H7O3S)2(C13H14N2)2]

  • Mr = 845.3

  • Orthorhombic, P n n a

  • a = 23.818 (2) Å

  • b = 17.4359 (10) Å

  • c = 9.3341 (10) Å

  • V = 3876.3 (6) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 0.64 mm-1

  • T = 273 K

  • 0.12 × 0.08 × 0.01 mm
Data collection

  • Bruker APEXII CCD area-detector diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2001[Bruker (2001). SAINT-Plus and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.927, Tmax = 0.994

  • 18799 measured reflections

  • 3374 independent reflections

  • 2761 reflections with I > 2[sigma](I)

  • Rint = 0.068
Refinement

  • R[F2 > 2[sigma](F2)] = 0.033

  • wR(F2) = 0.091

  • S = 1.08

  • 3374 reflections

  • 251 parameters

  • H-atom parameters not refined

  • [Delta][rho]max = 0.61 e Å-3

  • [Delta][rho]min = -0.67 e Å-3

Data collection: APEX2 (Bruker, 2004[Bruker (2004). APEX2. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT-Plus (Bruker, 2001[Bruker (2001). SAINT-Plus and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: BX2229 ).

Acknowledgements

The authors thank the NSFC (grant No. 20776081) and the Natural Science Foundation of Shandong Province (grant No. Y2006B37).

References

Bruker (2001). SAINT-Plus and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2004). APEX2. Bruker AXS Inc., Madison, Wisconsin, USA.
Hagrman, P. J., Hagrman, D. & Zubieta, J. (1999). Angew. Chem. Int. Ed. 38, 2638-2684.  [CrossRef]
Jia, H. P., Li, W., Ju, Z. F. & Zhang, J. (2007). Inorg. Chem. Commun. 10, 265-268.  [ISI] [CSD] [CrossRef] [ChemPort]
Kortz, U., Hamzeh, S. S. & Nasser, N. A. (2003). Chem. Eur. J. 9, 2945-2952.  [CrossRef] [ChemPort]
Li, H., Eddaoudi, M. O., Keffe, M. & Yaghi, O. M. (1996). Nature (London), 402, 276-279.
Liu, B., Li, X. M., Li, C. B., Gao, G. G. & Che, G. B. (2007). Chin. J. Struct. Chem. 26, 679-682.
Mock, W. L. & Morsch, L. A. (2001). Tetrahedron, 57, 2957-2964.  [ISI] [CrossRef] [ChemPort]
Seo, J. S., Whang, D., Lee, H., Jun, S. I., Oh, J., Jeon, Y. J. & Kim, K. (2000). Nature (London), 404, 982-986.  [PubMed] [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Wang, Y. T., Tang, G. M., Wu, Y., Qin, X. Y. & Qin, D. W. (2007). J. Mol. Struct. 831, 61-68.  [ISI] [CSD] [CrossRef] [ChemPort]
Xu, C., Mao, H. Y., Zhang, H. Y., Liu, H. L., Wu, Q. A., Hou, H. W. & Zhu, Y. (2004). Chin. J. Struct. Chem. 23, 567-570.  [ChemPort]
Yaghi, O. M., Li, H., Davis, C., Richardson, D. & Groy, T. L. (1998). Acc. Chem. Res. 31, 474-484.  [ISI] [CrossRef] [ChemPort]
Zhu, L. G., Cai, G. Q., Susumu, K. & Ho-Chol, C. (2002). Chin. J. Inorg. Chem. 18, 911-914.  [ChemPort]

Acta Cryst (2009). E65, m1116  [ doi:10.1107/S1600536809032760 ]

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