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Volume 65 
Part 9 
Pages m1045-m1046  
September 2009  

Received 21 July 2009
Accepted 30 July 2009
Online 8 August 2009

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Key indicators
Single-crystal X-ray study
T = 293 K
Mean [sigma](C-C) = 0.005 Å
R = 0.032
wR = 0.068
Data-to-parameter ratio = 14.0
Details
Open access

catena-Poly[[bis(2-hydroxy-2-phenylacetato-[kappa]2O1,O2)zinc(II)]-[mu]-1,2-di-4-pyridylethane-[kappa]2N:N']

Seung Man Yu,a Dong Hoon Shin,a Pan-Gi Kim,b* Cheal Kima and Youngmee Kimc*

aDepartment of Fine Chemistry, and Eco-Products and Materials Education Center, Seoul National University of Technology, Seoul 139-743, Republic of Korea,bDepartment of Forest & Environmental Resources, Kyungpook National University, Sangju 742-711, Republic of Korea, and cDepartment of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Republic of Korea
Correspondence e-mail: chealkim@sunt.ac.kr, ymeekim@ewha.ac.kr

The title compound, [Zn(C8H6O3)2(C12H12N2)]n, consists of [Zn(Hopa)2] (H2opa = 2-hydroxy-2-phenylacetic acid or mandelic acid) units bridged by 1,2-di-4-pyridylethane (bpe) ligands, forming a polymeric chain developing parallel to the b axis. The bridging bpe ligand is arranged around a twofold axis passing through the middle of the ethane C-C bond. The geometry around the ZnII ion is distorted octahedral, constructed by four O atoms from two Hopa- ligands and two N atoms from two bridging bpe ligands. O-H...O hydrogen bonds link the chains, forming a three-dimensional network.

Related literature

Transition metal ions are the major cationic contributors to the inorganic composition of natural water and biological fluids, see: Daniele et al. (2008[Daniele, P. G., Foti, C., Gianguzza, A., Prenesti, E. & Sammartano, S. (2008). Coord. Chem. Rev. 252, 1093-1107.]). For related structures, see: Balboa et al. (2008[Balboa, S., Carballo, R., Castineiras, A., Gonzalez-Perez, J. M. & Niclos-Gutierrez, J. (2008). Polyhedron, 27, 2921-2930.]); Beghidja et al. (2005[Beghidja, A., Hallynck, S., Welter, R. & Rabu, P. (2005). Eur. J. Inorg. Chem. pp. 662-669.]); Hao et al. (2009[Hao, H.-Q., Liu, W.-T., Tan, W., Lin, Z.-J. & Tong, M.-L. (2009). CrystEngComm, 11, 967-971.]); Lee et al. (2008[Lee, E. Y., Park, B. K., Kim, C., Kim, S.-J. & Kim, Y. (2008). Acta Cryst. E64, m286.]); Park et al. (2008[Park, B. K., Jang, K.-H., Kim, P.-G., Kim, C. & Kim, Y. (2008). Acta Cryst. E64, m1141.]); Shin et al. (2009[Shin, D. H., Han, S.-H., Kim, P.-G., Kim, C. & Kim, Y. (2009). Acta Cryst. E65, m658-m659.]); Wermester et al. (2007[Wermester, N., Aubin, E., Pauchet, M., Coste, S. & Coquerel, G. (2007). Tetrahedron Asymmetry, 18, 821-831.]); Yu et al. (2008[Yu, S. M., Park, C.-H., Kim, P.-G., Kim, C. & Kim, Y. (2008). Acta Cryst. E64, m881-m882.]).

[Scheme 1]

Experimental

Crystal data

  • [Zn(C8H6O3)2(C12H12N2)]

  • Mr = 551.90

  • Hexagonal, P 61 22

  • a = 11.1360 (6) Å

  • c = 33.110 (3) Å

  • V = 3555.9 (4) Å3

  • Z = 6

  • Mo K[alpha] radiation

  • [mu] = 1.09 mm-1

  • T = 293 K

  • 0.10 × 0.05 × 0.05 mm
Data collection

  • Bruker SMART CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 1997[Bruker (1997). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.933, Tmax = 0.944

  • 17715 measured reflections

  • 2347 independent reflections

  • 2045 reflections with I > 2[sigma](I)

  • Rint = 0.077
Refinement

  • R[F2 > 2[sigma](F2)] = 0.032

  • wR(F2) = 0.068

  • S = 1.04

  • 2347 reflections

  • 168 parameters

  • 1 restraint

  • H-atom parameters constrained

  • [Delta][rho]max = 0.22 e Å-3

  • [Delta][rho]min = -0.21 e Å-3

  • Absolute structure: Flack (1983[Flack, H. D. (1983). Acta Cryst. A39, 876-881.]), 870 Friedel pairs

  • Flack parameter: -0.002 (16)

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
O13-H13O...O12i 0.85 1.77 2.619 (3) 173
Symmetry code: (i) [x-y+1, x, z+{\script{1\over 6}}].

Data collection: SMART (Bruker, 1997[Bruker (1997). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 1997[Bruker (1997). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: PLATON (Spek, 2009[Spek, A. L. (2009). Acta Cryst. D65, 148-155.]); software used to prepare material for publication: SHELXL97.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: DN2478 ).

Acknowledgements

Financial support from the Korea Ministry of the Environment `ET-Human Resource Development Project' and the Cooperative Research Program for Agricultural Science & Technology Development (20070301-036-019-02) is gratefully acknowledged.

References

Balboa, S., Carballo, R., Castineiras, A., Gonzalez-Perez, J. M. & Niclos-Gutierrez, J. (2008). Polyhedron, 27, 2921-2930.  [ISI] [CSD] [CrossRef] [ChemPort]
Beghidja, A., Hallynck, S., Welter, R. & Rabu, P. (2005). Eur. J. Inorg. Chem. pp. 662-669.  [ISI] [CSD] [CrossRef]
Bruker (1997). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Daniele, P. G., Foti, C., Gianguzza, A., Prenesti, E. & Sammartano, S. (2008). Coord. Chem. Rev. 252, 1093-1107.  [ISI] [CrossRef] [ChemPort]
Flack, H. D. (1983). Acta Cryst. A39, 876-881.  [CrossRef] [details]
Hao, H.-Q., Liu, W.-T., Tan, W., Lin, Z.-J. & Tong, M.-L. (2009). CrystEngComm, 11, 967-971.  [ISI] [CSD] [CrossRef] [ChemPort]
Lee, E. Y., Park, B. K., Kim, C., Kim, S.-J. & Kim, Y. (2008). Acta Cryst. E64, m286.  [CSD] [CrossRef] [details]
Park, B. K., Jang, K.-H., Kim, P.-G., Kim, C. & Kim, Y. (2008). Acta Cryst. E64, m1141.  [CSD] [CrossRef] [details]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Shin, D. H., Han, S.-H., Kim, P.-G., Kim, C. & Kim, Y. (2009). Acta Cryst. E65, m658-m659.  [CSD] [CrossRef] [details]
Spek, A. L. (2009). Acta Cryst. D65, 148-155.  [ISI] [CrossRef] [details]
Wermester, N., Aubin, E., Pauchet, M., Coste, S. & Coquerel, G. (2007). Tetrahedron Asymmetry, 18, 821-831.  [ISI] [CSD] [CrossRef] [ChemPort]
Yu, S. M., Park, C.-H., Kim, P.-G., Kim, C. & Kim, Y. (2008). Acta Cryst. E64, m881-m882.  [CSD] [CrossRef] [details]

Acta Cryst (2009). E65, m1045-m1046   [ doi:10.1107/S1600536809030281 ]

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