Acta Cryst. (2009). E65, m1146  [ doi:10.1107/S1600536809033650 ]

Bis{2-[2-(dimethylamino)ethyliminomethyl]-4,6-disulfanylphenolato}cobalt(II) monohydrate

Y.-J. Cai, J. Li, P. Huang and Q.-F. Zeng

Abstract: In the title hydrated complex, [Co(C₁₁H₁₅N₂OS₂)₂]·H₂O, the Co^II atom (site symmetry 2) is coordinated by two O,N,N'-tridentate Schiff base ligands, resulting in a very distorted cis-CoO₂N₄ octahedral geometry for the metal ion. In the crystal, the water molecule (O-atom site symmetry 2) interacts with nearby complex molecules by way of bifurcated O-H(O,S) hydrogen bonds.

Online 29 August 2009

Copyright © International Union of Crystallography
IUCr Webmaster